We have investigated the phase diagram of Xe over a wide pressure-temperature range by molecular dynamics. The calculated melting curve is in good agreement with earlier experimental data. At a pressure of around 25 GPa and a temperature of about 2700 K we find a triple fcc-bcc liquid point. The calculated fcc-bcc boundary is in nice agreement with the experimental points, which, however, were ...

Densities in molten KCl, RbCI, T1C1, KC1-T1C1 and RbCl -TlCl at various temperatures (t °C) were measured to within ±0.1% by iridium pyknometry. For the pure melts the results fit empirical equations of the form Q=a—bt . The molar volumes at the melting points were derived and tested against other melting-point data for thermodynamic consistency. In the mixtures the volumes deviate from additiv...

Water soluble homo-base polynucleotide analogues were synthesized in which polyvinyl alcohol and partially phosphonated polyvinyl alcohol constituted the backbones,onto which were grafted uracil or adenine via 1,3-dioxane spacers formed by acetal formation with the 1,3-diol moieties in PVA. The resulting adenine-PVA polynucleotide analogs exhibited hyperchromic effects, which was not the case f...

In this work, new biodegradable ABCBA type pentablock copolymers with different mole ratio of L-lactide and PPDO-b-PEG-b-PPDO triblock copolymer were synthesized and characterized. In the first step, PPDO-b-PEG-b-PPDO triblock copolymer was synthesized via a ring-opening polymerization of P-DiOxanone (PDO) monomer with Poly (Ethylene Glycol) (P...

The deposition of x-ray energy resulting from the microexplosion i.o an inertial confinement fusion reactor and the subsequent thermal response of candidate wall coating and structural materials is examined. Evaporation losses and resulting melt layer thicknesses for these materials exposed to a variety of different x-ray energies and spectra are calculated. Softer x-ray energy spectra absorbed...

For several years, progress has been made in understanding surface melting as well as surface roughening of various crystals such as ice, lead, rare gases etc. A so-called quasi-liquid layer (QLL), caused by surface melting, is expected to influence the vapor growth mechanism of crystals at temperatures not far below their melting points. The effect of the self-diffusion coefficient D of a QLL ...

Grazing incidence small angle X-ray scattering (GISAXS) measurements reveal that superlattices of 1.7 nm diameter, gold (Au) nanocrystals capped with octadecanethiol become significantly more ordered when heated to moderate temperatures (50-60 °C). This enhancement in order is reversible and the superlattice returns to its initially disordered structure when cooled back to room temperature. Dis...

Introduction The multiple melting points of triglycerides have been known and studied for more than a century by numerous workers. The ability of fat to undergo polymorphic changes is important mainly due to its effect on product texture and appearance. Polymorphic resolidification during storage of cocoa butter into higher melting forms can destroy the smooth glossy appearance of a confectione...

In situ high P-T Raman measurements and optical observations of solid and fluid oxygen up to 1250 K between 8 and 25 GPa reveal the existence of a new molecular phase eta and strikingly unusual behavior of the melting curve. Three triple points were also identified in the P-T domain of the new phase. The data give a direct measure of the melting curve that greatly extends previous optical inves...