The title compound, Rb+·H3CN2O-, has been crystallized in liquid ammonia as a reaction product of the reductive ammonolysis of the natural compound streptozocin. Elemental rubidium was used as reduction agent as it is soluble in liquid ammonia, forming a blue solution. Reductive bond cleavage in biogenic materials under kinetically controlled conditions offers a new approach to gain access to s...

Fig. 6. Analysis of the volatile amines present in Chenopodium vulvaria L. Curve A: standard mixture ofmono-, diand tri-methylamines. Curve B: chromatogram of the amines present in an acid extract ofthe plant, showing the presence of only ammonia and trimethylamine. (Column length, 4ft.; liquid phase, hendecanol-iS% liquid paraffin (v/v); temp., 78 50; flow rate of nitrogen, 5.7 ml./min.; nitro...

Penta-ammine dioxide uranium(V) nitrate ammonia (1/1), [UO2(NH3)5]NO3·NH3, was obtained in the form of yellow crystals from the reaction of caesium uranyl nitrate, Cs[UO2(NO3)3], and uranium tetra-fluoride, UF4, in dry liquid ammonia. The [UO2]+ cation is coordinated by five ammine ligands. The resulting [UO2(NH3)5] coordination polyhedron is best described as a penta-gonal bipyramid with the O...

BACKGROUND Ammonia and endogenous benzodiazepines (BDZs) are two of the most important agents among those taken into consideration in the pathogenesis of hepatic encephalopathy (HE). METHODS Venous ammonia and endogenous BDZs sera levels were assayed in 58 liver cirrhosis patients (34 male, 24 female) free of commercial BDZs. Endogenous BDZs were measured by binding assay after high-performan...

Ammonia is stored as a liquefied raw material it used in the fertilizer and cooling industries. The use of multistage compressors during storage essential, boiling point very low (-33°C) due to typical petroleum derivative. Because pressure-temperature optimization with single-stage compressor does not allow ammonia be under atmospheric conditions. condenser throttling valves systems together m...

Combining infrared spectroscopy and molecular dynamics simulations, we have investigated the structural and dynamical properties of ammonia from liquid state (T = 220 and 303 K) up to the supercritical domain along the isotherm T = 423 K. Infrared spectra show that the N-H stretching and bending modes are significantly perturbed which is interpreted as a signature of the change of the local env...

The dissolution of the ternary material K6Rb6Si17 in liquid ammonia yields the solvate compound Rb4Si9 · 5NH3, which contains fourfold negatively charged nine atom silicon clusters Si94−. Using additionally the [2.2.2] cryptand during the dissolution results in the solvate [K(2.2.2crypt)]2Si5 · 4NH3 , in which the Si52− anion is present in the crystal structure. The Si52− anion has the shape of...