Based on polycyclic aromatic azomethine ylides (PAMYs), a metal-free "cycloaddition-planarization-sequence" is proposed, providing a unique entry to extended nitrogen-containing polycyclic aromatic hydrocarbons (N-PAHs). This method is highly versatile, as the structure of unprecedented N-PAHs can be tailored by the dipolarophile in the crucial 1,3-cycloaddition-reaction. Linear, as well as fiv...

Photocatalytic conversion of carbon dioxide (CO(2)) to hydrocarbons such as methanol makes possible simultaneous solar energy harvesting and CO(2) reduction, two birds with one stone for the energy and environmental issues. This work describes a high photocatalytic conversion of CO(2) to methanol using graphene oxides (GOs) as a promising photocatalyst. The modified Hummer's method has been app...

Researchers devote to design catalytic systems with higher activity, selectivity, and stability ideally based on cheap and earth-abundant elements to reduce CO2 to value-added hydrocarbon fuels under mild conditions driven by visible light. This may offer profound inspirations on that. A bi-functional molecular iron catalyst designed could not only catalyze two-electron reduction from CO2 to CO...

High-efficiency and high-selectivity catalytic oxidation of alkanes under mild conditions with air is a major aim of current catalytic chemistry and chemical production. Despite extensive development efforts on new catalysts for cyclohexane oxidation, current commercial processes still suffer from low conversion, poor selectivity, and excessive production of waste. Here, we present the design a...

We report a facile hydrolytic process for the preparation of CQDs/SiO2 porous nanocomposites, which show high catalytic activity and stability for the selective oxidation of cis-cyclooctene under visible light irradiation, with TBHP as a radical initiator and oxygen (in the air) as an oxidant at 80 °C.

The development of an "artificial photosynthetic system" (APS) having both the analogous important structural elements and reaction features of photosynthesis to achieve solar-driven water splitting and CO₂ reduction is highly challenging. Here, we demonstrate a design strategy for a promising 3D APS architecture as an efficient mass flow/light harvesting network relying on the morphological re...

results the soil was largely composed of silt and clay (silt:41 - 42%, clay: 40 - 43%, sand: 15 - 18%). the average moisture content of the saturated soil was 12.96%,; average electricity conductivity was 18.64 dsm-1; average ph of the paste was 8.36; and average percentage of organic carbon was 0.19%. result of the laboratory analysis reported the average content of total nitrogen as 0.026%, p...