The synthesis of tetra-ortho-substituted biaryl naphthalenes, including examples bearing multiple ortho-isopropyl groups, has been developed via a catalytic rearrangement process.

The amplifying asymmetric autocatalysis discovered by Soai and co-workers is dependent on the unique steric properties of the isopropyl group.

Plutella xylostella cause considerable harm to the production of broccoli, Chinese cabbage, cabbage and cauliflower. The control P. is mainly performed using commercial insecticides, which have even led emergence resistant populations. Two easily available natural products found in different plants essential oil, thymol eugenol, stand up as possible novel agents this pest. In work a series alky...

We describe convenient preparations of N,N′-dialkyl-1,3-propanedialdiminium chlorides, N,N′-dialkyl-1,3-propanedialdimines, and lithium N,N′-dialkyl-1,3-propanedialdiminates in which the alkyl groups are methyl, ethyl, isopropyl, or tert-butyl. For dialdiminium salts, N2C3 backbone is always trans-s-trans configuration. Three isomers present solution except for tert-butyl compound, only two pre...