Use of hydrogen in fuel cells requires catalysts that are tolerant to oxygen and are able to function in the presence of poisons such as carbon monoxide. Hydrogen-cycling catalysts are widespread in the bacterial world in the form of hydrogenases, enzymes with unusual active sites composed of iron, or nickel and iron, that are buried within the protein. We have established that the membrane-bou...

In meeting the need for environmental remediation in wastewater treatment and the development of popular sulfate-radical-based advanced oxidation processes (SR-AOPs), a series of Co/Fe-based catalysts with confirmed phase structure were prepared through extended soft chemical solution processes followed by atmosphere-dependent calcination. Powder X-ray diffraction (XRD), scanning electron micro...

Earth-abundant metal catalysts are critically needed for sustainable chemical synthesis. Here we report a simple, cheap and effective strategy of producing novel earth-abundant metal catalysts at metal-organic framework (MOF) nodes for broad-scope organic transformations. The straightforward metalation of MOF secondary building units (SBUs) with cobalt and iron salts affords highly active and r...

This study examined the ability of the synthetic mordenite nanocrystal to remove Tl(III) and As(III) from an aqueous solution. The determination of the concentration changes of H+ and OH- quantities in the acidic (pH 3) and alkali (pH 9) treated mordenite nanocrystals were done by the potentiometric titration curves. The maximum uptake capacities (Qmax) of these metal ions using the mordenite i...

The Fischer-Tropsch synthesis (FTS) has been recognized as a heterogeneous surface-catalyzed polymerization process. During this process, CHx monomers formed via the hydrogenation of adsorbed CO on transition metals produce hydrocarbons and oxygenates with a broad range of chain lengths and functional groups. A series of Fe/Cu Fischer-Tropsch synthesis catalysts incorporated with a calcium prom...

Syngas from biomass gasification is being developed for alternative feedstock in the chemical industry. Palm kernel shell which generated palm oil industry can be potentially used as raw material process. The purpose of this study was to investigate use modified natural zeolite catalysts steam shells. Mordenite type by acid leaching a tar cracking catalyst. Steam conducted at temperature range ...

The application of a variety of iron complexes with chelating amine ligands as pre-catalysts in the representative cross-coupling of 4-tolylmagnesium bromide with cyclohexyl bromide was investigated. The results from this study indicate the performance of the pre-catalyst is inversely proportional to the strength of the chelate or macrocyclic effect of the amine ligand, as determined by the pro...

Iron oxide microtubules produced by a species of iron-oxidizing bacteria, Leptothrix ochracea, have been expected to be useed as unique multifunctional materials such as catalysts scaffolds, pigments, and magnetic materials. However, their structural characteristics and formation mechanism are still ambiguous. The detailed features of the microtubules were characterized through electron microsc...

The adsorption of alkanes and alkenes on zeolites is investigated by comparing the adsorption characteristics for three types of zeolite: ferrierite, ZSM-5, and mordenite. The activation energy for the diffusion of propane and n-butane on ferrierite and the heat of adsorption of C(2)-C(4) alkanes and alkenes on zeolites and silica are estimated based on Fourier transform infrared spectroscopy, ...

The amphipolar iron(III) corrole 1-Fe is one of the most efficient catalysts for the decomposition of peroxynitrite, the toxin involved in numerous diseases. This research focused on the mechanism of that reaction at physiological pH, where peroxynitrite is in equilibrium with its much more reactive conjugated acid, by focusing on the elementary steps involved in the catalytic cycle. Kinetic in...