Microwave sintering (MWS) of commercially available 15-nm-size nanocrystalline TiN powder was studied. Densification kinetics and grain growth mechanisms of nano-TiN were evaluated using non-isothermal heating up to 1500 °C with variable heating rates. A true nanocrystalline ceramic with ~80-nm-size grains and 94.5 % theoretical density was obtained via MWS consolidation at 1400 °C. At higher t...

Measurements of the elastic constants,the specific heat and the entropy of grain boundaries have been performed by utilizing ultra-fine grained materials (Pd, 6nm grain size; Mg, 12 nm grain size; CaF2, 7 nm grain size) about 30 to 50 vol% of which consist of grain boundaries. The results obtained suggest that (1) The interatomic potentials in grain boundaries in metals differ from the lattice ...

Twenty-eight coupled observations of flow, transport, and bed surface grain size distribution were made in a laboratory flume using a wide range of flows and a sediment with a very poorly sorted, bimodal grain size distribution. These observations permit the transport rates of individual size fractions to be scaled by the proportion of each size immediately available for transport on the bed su...

Accumulative roll-bonding (ARB) is a severe plastic deformation process that is using rolling to produce ultrafine grains in coarse grained metallic materials. In this study, ARB has been applied on 70/30 brass up to 6 cycles at ambient temperature and non-lubricated conditions to apply a true strain up to 4.8 Von Mises strain. Microstructures of ARBed brass samples were characterized by scanni...

Magnetic and electric properties are investigated for the nanosized YMnO3 samples with different grain sizes (25 nm to 200 nm) synthesized by a modified Pechini method. It shows that magnetic and electric properties are strongly dependent on the grain size. The magnetic characterization indicates that with increasing grain size, the antiferromagnetic (AFM) transition temperature increases from ...

Understanding the influence of grain boundaries (GBs) on the electrical and thermal transport properties of graphene films is essentially important for electronic, optoelectronic and thermoelectric applications. Here we report a segregation-adsorption chemical vapour deposition method to grow well-stitched high-quality monolayer graphene films with a tunable uniform grain size from ∼200 nm to ∼...

The effects of rare earth addition and hot extrusion process on the grain refinement of magnesium alloy were studied. The as-cast Mg-6Al-1Zn (AZ61) alloy had the average grain size of ~ 64 µm and its microstructure consisted of α-Mg and Mg17Al12 phase. By partial substitution of Al with Gd to reach Mg-4.8Gd-1.2Al-1Zn alloy, it was observed that the Mg17Al12 phase disappeared and two new interme...

Grain size is an important parameter controlling the mechanical behavior and useful life of turbine disks. During heat treatment above the gamma prime (γ′) solvus the grain size increases dramatically as the γ′ particles dissolve. The grain size then stagnates as the volume fraction of the γ′ phase approaches zero. In general, the grain size at stagnation cannot be described by classic Zener pi...

The distribution of the characteristic texture components between the ferrite grains of different size classes has been studied in a steel with 0.082%C, 1.54% Mn, 0.35% Si, 0.055%Nb and 0.078%V after different rolling schedules with a final rolling temperature above or below Ar3. Microstructures and textures were characterized by means of optical microscopy and orientation microscopy. A strong ...

Systematic experiments have been performed to investigate the rate sensitivity of deformation in fully dense nanocrystalline Ni using two different experimental techniques: depth-sensing indentation and tensile testing. Results from both types of tests reveal that the strain-rate sensitivity is a strong function of grain size. Specifically microcrystalline and ultra-fine crystalline pure Ni, wi...