Many of water's peculiar physical properties are still not well understood, and one of the most important unresolved questions is its glass transition related dynamics. The consensus has been to accept a glass transition temperature (T(g)) around 136 K, but this value has been questioned and reassigned to about 165 K. We find evidence that the dielectric relaxation process of confined water tha...

Birefringence of oxide glass fibers drawn from glass melts through an orifice has been detected previously [H. Stockhorst, R. BruÈckner, J. Non-Cryst. Solids 49 (1982) 471; H. Stockhorst, R. BruÈckner, J. Non-Cryst. Solids, 86 (1985) 105.] This birefringence is a measure of anisotropy in glass structure that can influence fiber performance properties. Birefringence is produced during fiber draw...

High-temperature high-vacuum electrostatic levitation ~HTHVESL! and differential scanning calorimetry ~DSC! were combined to determine the hemispherical total emissivity eT , and the specific heat capacity cp , of the undercooled liquid and throughout the glass transition of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 bulk metallic glass forming alloy. The ratio of cp /eT as a function of undercooling w...

Concentrated colloidal suspensions are a well-tested model system which has a glass transition. Colloids are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the particles are roughly analogous to individual molecules in a traditional glass. Because the particle size can be large (100 nm 1000 nm), these samples can be studied...

Temperature modulated differential scanning calorimetry measurements on Agy(GexSe1−x )1−y glasses provide evidence for bimodal glass transition temperatures in Se-rich glasses (x < 1/3). At x = 0.20 and 0.25, thermal measurements performed as a function of Ag content in the 0 y 0.25 range reveal that the additive (Ag) segregates into an Ag2Se-rich glass phase, possessing a characteristic glass ...

Ultra optical glasses are proposed for attaining noble glazes of high reflection and shine. In addition, these glasses can be used as semi-mirrors and optical instruments. In this reseach attempts were devoted mainly to introduce a glass system with the highest possible refractive index in which the highest reflection is desirable. Thus different amounts of heavy metal oxides modifiers, such as...

We report idealized mode-coupling theory results for the glass transition of ensembles of model fullerenes interacting via phenomenological two-body potentials. Transition lines are found for C60, C70, and C96 in the temperature-density plane. We argue that the observed glass transition behavior is indicative of kinetic arrest that is strongly driven by the interparticle attraction in addition ...

The static and dynamic properties of ring polymers in concentrated solutions remains one of the last deep unsolved questions in polymer physics. At the same time, the nature of the glass transition in polymeric systems is also not well understood. In this work, we study a novel glass transition in systems made of circular polymers by exploiting the topological constraints that are conjectured t...

We find that the density dependence of the glass transition temperature of Lennard-Jones (LJ) and Weeks-Chandler-Andersen (WCA) systems can be predicted from properties of the zero-temperature (T=0) glasses. Below a crossover density ρs, LJ and WCA glasses show different structures, leading to different vibrational properties and consequently making LJ glasses more stable with higher glass tran...