in the present study, silver oxyfluoride modified silver electrode was employed to electrocatalytic oxidation of isoniazid. the process of oxidation and its kinetics were established by using cyclic voltammetry, chronoamperometry and amperometry techniques. the modified electrode shows a stable and linear response in the concentration range of 3×10−4 to 2.1×10−3 mol l-1 with a correlation coeff...

a physic-mathematical model has been developed that is suitable for biosensors incorporating membranes and bisubstrate enzymes. the set of equations regarding the transport of reactants across the membrane, the bisubstrate enzymatic reaction, back diffusion of reactants and reaction products, are written down and simultaneously solved and transient response of the electrode is determined as a f...

a thin film of epinephrine (ep) was electrochemically deposited on the surface of glassy carbon electrode previously activated in nahco3 solution. the cyclic voltammograms of the modified electrode indicate that the surface confined ep are strongly dependent on the solution ph, as expected for quinone/hydroquinone functionalities. the ep-modified glassy carbon electrode exhibited catalytic acti...

A full three-dimensional, single phase computational fluid dynamics model of a proton exchange membrane fuel cell (PEMFC) with both the gas distribution flow channels and the Membrane Electrode Assembly (MEA) has been developed. A single set of conservation equations which are valid for the flow channels, gas-diffusion electrodes, catalyst layers, and the membrane region are developed and numer...

A two-dimensional, unsteady, isothermal and two-phase flow of reactant-product mixture in the air-side electrode of proton exchange membrane fuel cells (PEMFC) is studied numerically in the present study. The mixture is composed of oxygen, nitrogen, liquid water and water vapor. The governing equations are two species conservation, a single momentum equation for mobile mixture, liquid mass cons...

Although the standard hydrogen electrode is never used in practice today, it is the standard against which all other standard electrode potentials are referenced. Surprisingly, even though a drawing of the standard hydrogen electrode appears in most introductory textbooks on analytical chemistry, very few of the electrodes would work in practice. The answer why none of the depicted electrodes (...

In this study, the use of the three-layer feed forward neural network has been investigated for estimating of infinite dilute diffusion coefficient ( D12 ) of supercritical fluid (SCF), liquid and gas binary systems. Infinite dilute diffusion coefficient was spotted as a function of critical temperature, critical pressure, critical volume, normal boiling point, molecular volume in normal boilin...