Proton tautomerism is a general phenomenon in organic molecules and plays a vital role in many fields of chemistry and biochemistry. The tautomerism of salicylideneanilines [eq(1)] has attracted a considerable attention because it is closely related to thermoand photochromism. Salicylideneanilines greatly favor the enol form over the cis-keto form in the gas phase. We demonstrate here that the ...

To account for the explanation of an eventual sensing and catalytic behavior of rhombohedral In2O3 (rh-In2O3) and the dependence of the metastability of the latter on gas atmospheres, in situ electrochemical impedance spectroscopic (EIS), Fourier-transform infrared spectroscopic (FT-IR), in situ X-ray diffraction and in situ thermogravimetric analyses in inert (helium) and reactive gases (hydro...

Early X-ray observations suggested that the intracluster medium cools and condenses at the centers of clusters, leading to a cooling flow of plasma in the cluster core. The increased incidence of emission-line nebulosity, excess blue light, AGN activity, and molecular gas in the cores of clusters with short central cooling times seemed to support this idea. However, high-resolution spectroscopi...

Early X-ray observations suggested that the intracluster medium cools and condenses at the centers of clusters, leading to a cooling flow of plasma in the cluster core. The increased incidence of emission-line nebulosity, excess blue light, AGN activity, and molecular gas in the cores of clusters with short central cooling times seemed to support this idea. However, high-resolution spectroscopi...

The objective of the study is to observe the anti-motion sickness effect of volatile oil extract of Pinelia ternata in rats, compare the strength of anti-motion sickness action between the Pinelia ternata volatile oil extract and the dimenhydrinate, and analyze the constituents in volatile oil of Pinelia ternata. Rats with frequency is 0.05Hz, the peak speed of 240°/s rotated to stimulate, evok...

A new single-drop microextraction approach is proposed for the extraction of compounds with a wide range of volatilities from tap water samples with separation/detection by gas chromatographymass spectrometry. This new microextraction mode is called direct immersion-headspace-single drop microextraction (DI-HS-SDME). Trihalomethanes (THMs), hydrocarbons with low molecular weight (benzene, ethyl...

Absorption and fluorescence characteristics of aqueous solutions of salts, sugars, and amino acids were studied using UV-vis spectroscopy and spectrofluorometry. Motivation stemmed from unanticipated absorption spectral and fluorescence features of the "exclusion zone" seen adjacent to various hydrophilic surfaces. Those features implied a structure distinct from that of bulk water (Adv. Colloi...

Raman spectroscopic measurements of simple hydrogen and tetrahydrofuran+hydrogen sII clathrate hydrates have been performed. Both the roton and vibron bands illuminate interesting quantum dynamics of enclathrated H(2) molecules. The complex vibron region of the Raman spectrum has been interpreted by observing the change in population of these bands with temperature, measuring the absolute H(2) ...