The selectivity of immobilised 8-hydroxyquinoline for lead is shown to be improved by the use of masking agents during pre-concentration, prior to determination by flame atomic absorption spectrometry. Interference by iron, copper, aluminium and zinc is suppressed by including triethanolamine, thiourea, fluoride, acetylacetone or cyanide in the buffer as masking agents. Species such as iron or ...

28 Cadmium and lead accumulate in the deciduous teeth of children with celiac disease or food allergies Abstract The objective of this study was to examine the relative levels of cadmium, lead and calcium in deciduous teeth of children with celiac disease or food allergies from an industrial area of Poland compared to healthy controls. Using flame atomic absorption spectrometry it was found tha...

Cigarettes and tobacco products are consumed in large amounts by human beings in the world. Also, tobacco is one of the most important agricultural products in Turkey. The accumulation of heavy metals in tobacco leaves in accordance with a possible risk of transferring them to people by smoke is well known. This study was carried out to estimate trace metal and mineral levels in tobacco and cig...

a chelating resin of polystyrene divinylbenzene resin functionalized by 1-(2-pyridylazo) 2- naphtol (psdvb-pan) has been synthesized and its sorption properties have been investigated for preconcentration and determination of cadmium at μg/l level by flame atomic absorption spectrometry. the procedure is based on the sorption of cd(ii) ions on a minicolumn of synthesized chelating resin. the...

the flame propagation through a coal dust-air mixture in a spherical vessel was studied by means of a one-dimensional, arrhenius-type kinetics and quasi-steady model. the model includes the evaporation of the volatile matter of dust particles into a known gaseous fuel (methane) and the single-stage reaction of the gas-phase combustion. effect of venting devices as safety idea and the radiation ...

premixed combustion is widely used for reducing pollutant emission from combustion chambers. however, these systems may be sensitive to complex phenomena such as flashback. in the present study flame, flashback and structure of premixed laminar flames are investigated theoretically. the mathematical model includes the axi-symmetric continuity, navier stocks, energy, and species equations. combu...

A fast method for separation, preconcentration and determination of cadmium in drinking (source, well, tap) and water for irrigation is described. Iron(III) hexamethylenedithiocarbamate, Fe(HMDTC)3, has the role of colloid precipitate flotation collector. The determination of cadmium in final water solutions preconcentrated by flotation can be performed by flame (FAAS) or electrothermal atomic ...

abstract: An analytical method validation represents a complete investigation of the materials’ properties, following certain steps, being necessary for “proving the fit for purpose of an analytical method”. The validation procedure demonstrate that a defined validation protocol for an analytical method applied to a specified testing material and a defined concentration of the analyt – named an...

An automated method based on the principles of flow-injection analysis is proposed for the enzymatic determination of sodium ion in serum. The method relies on the activation of beta-galactosidase by the analyte. The features of the proposed method include linear range between 1 and 1700 mumol/L, a sampling rate of 50 samples/h, a sample volume of 50 microL, and the absence of interferences fro...