Combining ultrasonic irradiation and the Fenton process as a sono-Fenton process, chemical oxygen demand (COD) in refinery wastewater was successfully eliminated using response surface methodology (RSM) with central composite design (CCD). The impact of two main influential operational parameters (iron dosage reaction time) on COD removal from generated by an Iraqi petroleum facility explored. ...

A series of photo-Fenton reactions have been performed for the degradation of 2,4,6-trinitrotoluene (TNT) in a 4.2-l reactor. The degradation reaction rate of TNT followed a pseudo-first-order behavior; and the rate constants for 2.4mW cm(-2)UV only, 2.4mW cm(-2)UV/H(2)O(2), Fenton, photo-Fenton (2.4mW cm(-2)) and photo-Fenton (4.7mW cm(-2)) were 0.002min(-1), 0.007min(-1), 0.014min(-1), 0.025m...

The removal efficiency of 4-chlorophenol with different advanced oxidation processes have been studied. Oxidation experiments were carried out using two 4-chlorophenol concentrations: 100 mg L and 250 mg L and UV generated from a KrCl excilamp with (molar ratio H2O2: 4-chlorophenol = 25:1) and without H2O2, and, with Fenton process (molar ratio H2O2:4chlorophenol of 25:1 and Fe concentration of...

The blooming of the world’s human population and transition diet into a more westernized, high-protein has accelerated production slaughterhouse wastewater (SWW) as number meat processing plants (MPP) increased in past few decades. Conventional treatment processes (CTP) used treating SWW, such anaerobic processes, membrane electrocoagulation, have significant limitations, low efficiency, tenden...

Various aspects of the participation of Fenton chemistry in biology and medicine are reviewed. Accumulated evidence shows that both hydroxyl radical and ferryl [Fe(IV)=O]2+ can be formed under a variety of Fenton and Fenton-like reactions. Some examples of metal-independent hydroxyl radical production are included. Extracellular Fenton reaction is illustrated by the white rot and brown rot wood...

The hydroxyl radical (OH radical) formation rates from the photo-Fenton reaction in river and rain water samples were determined by using deferoxamine mesylate (DFOM), which makes a stable and strong complex with Fe(III), resulting in a suppression of the photo-Fenton reaction. The difference between the OH radical formation rates with and without added DFOM denotes the rate from the photo-Fent...

The present study was conducted in order to investigate the efficiency of different advanced oxidation processes both individually and combination with biological method for removal color chemical oxygen demand (COD) from wastewater pulp paper industry. Advanced include ozone, Fenton, hydrogen peroxide, photo-Fenton. Biologically treated successively subjected (AOPs). optimum conditions ozone t...