This study investigated the adsorption of the heavy metal ions Pb(II), Cu(II), Cd(II), Zn(II), and Ni(II) on a lignin isolated from black liquor, a waste product of the paper industry. Lignin has affinity with metal ions in the following order: Pb(II)>Cu(II)>Cd(II)>Zn(II)>Ni(II). The adsorption kinetic data can be described well with a pseudosecond-order model and the equilibrium data can be fi...

The adsorption potential of clay and sandy soil to remove benzene from liquid-phase system was examined. A series of batch adsorption tests were carried out for various concentrations of benzene (50 250 mg/l) in tightly corked 1000 ml flasks for clay and sandy soil, respectively. Equilibrium and kinetics data were obtained from the batch experiments. Adsorption increased with increasing initial...

bioremediation of heavy metals remains a major challenge in environmental biotechnology. biosorption is a novel technique for decreasing metal ion content in the waste water. biosorption experiments for cu (ii) were investigated in this study using bacteria isolated from the industrial effluent. the results showed that the dead cells of pseudomonas sp. were an efficient adsorbent of cu (ii). fo...

the modified surface of typha latifolia l. root (mstl), as an alternative economical adsorbent, wasused for the removal of ni (ii) and cd(ii) ions from aqueous solutions. the effect of initial ph, initialconcentration of metal ion, and contact time was investigated in a batch system at room temperature.the kinetics data could be fitted well by pseudo-second-order model with correlation coeffici...

The adsorption of chromium(VI) ions from aqueous solutions has been investigated on Neem sawdust (NS), Mango sawdust (MS), Wheat shell (WS), Sugarcane bagasse (SB) and Orange peel (OP). The adsorbent which showed highest chromium(VI) removal was Neem sawdust. The influence of pH, contact time, biomass dosage and initial metal concentration on biosorption was investigated. The biosorptive capaci...

Spin-polarized density functional theory computations have been carried out to study the stable adsorption configurations of Cun (n = 1-7, 13) on Fe and Fe3C surfaces for understanding the initial stages of copper promotion in catalysis. At low coverage, two-dimensional aggregation is more preferred over dispersion and three-dimensional aggregation on the Fe(110) and Fe(100) surfaces as well as...

A review of the literature about calculating the adsorption properties of arsenic onto mineral models using density functional theory (DFT) is presented. Furthermore, this work presents DFT results that show the effect of model charge, hydration, oxidation state, and DFT method on the structures and adsorption energies for As and As onto Fe-(oxyhydr)oxide cluster models. Calculated interatomic ...