The cell potential of the cell containing two ion-selective electrodes (ISE), Na-ISE | NaClO4 (m), PEG 4000 (Y), H2O (100-Y) | ClO4-ISE has been measured at temperatures of (288.15, 298.15, and 308.15) K as a function of the weight percentage Y of PEG 4000 in a mixed solvent at a 1 Mpa and the standard state for measured activity coefficients will be ...

Two overall neutral surfaces with positively and negatively charged domains ("patches") have been shown in recent experiments to exhibit long-range attraction when immersed in an ionic solution. Motivated by the experiments, we calculate analytically the osmotic pressure between such surfaces within the Poisson-Boltzmann framework, using a variational principle for the surface-averaged free ene...

This work presents a finite volume method used to solve the relevant coupled equations for general electro-osmotic flows of viscoelastic fluids, using the upper-convected Maxwell and the simplified Phan-Thien–Tanner models. Three different implementations of the electro-osmosis physical models were carried out, which depend on the required level of approximation. In the first implementation, th...

A new theory model based on the local composition concept (TNRF-modified NRTL (TNRF-mNRTL) model) was developed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. An equation represented the activity coefficient of solvent was derived from the proposed excess Gibbs energy equation. The short-range contribution of interaction ...

The first excited $$J^{\pi }=0^+$$ state of $$^{12}$$ C, the so-called Hoyle state, plays an essential role in a triple- $$\alpha $$ ( $$^{4}$$ He) reaction, which is main contributor to synthesis C burning star. We investigate Coulomb screening effects on energy shift thermal plasma environment using precise three- model calculations. effect between clusters taken into account within Debye-Hüc...

Using both theoretical modeling and computer simulations we study a model system for DNA interactions in the vicinity of charged membranes. We focus on the polarization of the mobile charges in the membranes due to the nearby charged rods (DNA) and the resulting screening of their fields and inter-rod interactions. We find, both within a Debye-Hückel model and in Brownian dynamics simulations, ...

Abstract The electroosmotic flow of non-Newtonian fluid–Eyring fluid in microparallel pipes under high zeta potential driven by the combination pressure and electric force is studied. Without using Debye–Hückel (DH) linear approximation, numerical solutions distribution velocity obtained finite difference method are compared with analytical approximate DH approximation. results show that this a...

The name Ising has come to stand not only for a specific model, but for an entire universality class arguably the most important such class in the theory of critical phenomena. I review several examples, both in and out of equilibrium, in which Ising universality appears or is pertinent. The “Ornstein-Zernike” connection concerns a thermodynamically self-consistent closure of the eponymous rela...