The aim of this research is to develop new mordants and a wide range of colors for natural dyeing of silk. In this study, two new erbium(ΙΙΙ) complexes, [Er(AO)(H2O)7](OAc)3 and [Er(AMH)(H2O)6](OAc)3 (AO = acridine orange, AMH = azomethine-H, and OAc = acetate anion), were synthesized, characterized and used as a mordant for the natural dyeing of silk yarns with an aqueous extract of green waln...