a type of novel hypercross-linked fiber adsorbent was obtained by sulfonation and cross-linking reaction of polypropylene fiber grafted styrene-divinylbenzene. the aim of the fiber sulfonation and cross-linking method was to prepare rigid three dimensional networks in the entire fiber and change the ion exchange capacity of fiber. the hypercross-linked fiber adsorbent possesses a principally di...

styrene nanocomposites were synthesized by in-situ atom transfer radical polymerization at 110oc. the variations of monomer conversion and the linearity of semilogarithmic kinetic plot, some signs of living polymerizationand constant radical concentration in the reaction medium, were revealed by gas chromatography technique (gc). according to the gel permeation chromatography (gpc) results, the...

the oxidation of n-pentanol by tetramethylammonium fluorochromate in acidic solution wasstudied using spectrophotometric technique. the reaction was arranged to be under pseudo firstorderconditions respect to the oxidant. a michaelis-menten type kinetic was observed respect tothe substrate. the reaction is catalyzed by hydrogen ions. dependences of the reaction rates ontemperature and different...

conclusions changes of ph could remarkably affect the efficiency and oxidation rate of mtbe. in particular, the amount of kap in terms of oxidation declines substantially by moving away from the optimum ph range. in this study, ph 3.5 was considered as the optimal ph in h2o2/nzvi/ultrasonic oxidation process, with the elimination of about 89.56% of the high mtbe concentration. in general, we ca...

A partially fluorine substituted hydroxyapatite- (FHA-) coated Mg-Zn alloy was prepared to investigate the interfacial behavior of degradable Mg-based biomaterials with degradable bioactive coatings in a cell culture environment. Peaks from the results of X-ray diffraction (XRD) were characterized and compared before and after cell culture. It was found that Ca-P, including poorly crystalline i...

We compared growth kinetics of Prorocentrum donghaiense cultures on different nitrogen (N) compounds including nitrate (NO3-), ammonium (NH4+), urea, glutamic acid (glu), dialanine (diala) and cyanate. P. donghaiense exhibited standard Monod-type growth kinetics over a range of N concentraions (0.5-500 μmol N L-1 for NO3- and NH4+, 0.5-50 μmol N L-1 for urea, 0.5-100 μmol N L-1 for glu and cyan...

Macromolecular crowding is one of the key characteristics of the cellular environment and is therefore intimately coupled to the process of protein folding in vivo. While previous studies have provided invaluable insight into the effect of crowding on the stability and folding rate of protein tertiary structures, very little is known about how crowding affects protein folding dynamics at the se...

Abstract In an immersive virtual environment, it was investigated how the perception of body kinetics contributes to social distance behavior when facial expression and other physical properties a interaction partner cannot be perceived. Based on point light displays, both subject were depicted as stick figures, moving simultaneously in same space. addition, effects relevant psychological facto...

The performance of sulfate-reducing permeable reactive barriers (PRB) used for the treatment of acid-mine drainage is critically affected by kinetics of cellulose decomposition and substrate production, as well as by kinetics of sulfate reduction and methanogenesis. When biofilm models are considered, the rate of substrate diffusion into the biofilm also affects performance. In this regard, res...

Kinetics and a mechanistic investigation of the reaction between dimethyl acetylenedicarboxcylate (DMAD) and saccharin (N-H heterocyclic compound) has been spectrally studied in methanol environment in the presence of triphenylarsine (TPA) as a catalyst. Previously, in a similar reaction, triphenylphosphine (TTP) (instead of triphenylarsine) has been employed as a third reactant (not catalyst) ...