نتایج جستجو برای: electrochemical potential
تعداد نتایج: 1111326 فیلتر نتایج به سال:
Titania nano particles were synthesized at carbon paste electrode by cyclic voltammetry and then it was employed for the determination of acetaminophen in phosphate buffer at pH 7.4. Carbon paste electrode with titania nano particle displayed excellent electrochemically catalytic activities by shifting the oxidation potential of acetaminophen towards the negative side. The mass transfer process...
The paper presents results of the study on electrochemical potentials of metallic dental materials. Seven alloys, amalgam and chromium-nickel steel were examined as well as the effect of the solution conductivity ranging from 12.5 μS/cm to 2.01 mS/cm and solution pH within the range of 5.5 to 11.2 on electrochemical potentials of the materials. Amalgam presented with the lowest changes of the s...
The adsorptive and electrochemical behaviors of clozapine (CLZ) were investigated on a glassy carbon electrode that was electrochemically treated by anodic oxidation at +1.8 V, following potential cycling in the potential range from -0.8 to 1.0 V vs. Ag/AgCl reference electrode. Based on the obtained electrochemical results, an electrochemical-chemical (EC) mechanism was proposed to explain the...
In this work, we have designed and developed a novel and cost effective virtual electrochemical analyzer for the measurement of NO in exhaled breath and from hydrogen peroxide stimulated endothelial cells using home-made potentiostat. Here, data acquisition system (NI MyDAQ) was used to acquire the data from the electrochemical oxidation of NO mediated by copper, zinc superoxide dismutase (Cu,Z...
Reactive interface patterning promoted by lithographic electrochemistry serves as a method for generating submicrometer scale structures. We use a binary-potential step on a metallic overlayer on silicon to fabricate radial patterns of cobalt oxide on the nanoscale. The mechanism for pattern formation has heretofore been ill-defined. The binary potential step allows the electrochemical boundary...
A miniaturised electrochemical cell design for Electron Paramagnetic Resonance (EPR) studies is reported. The cell incorporates a Loop Gap Resonator (LGR) for EPR investigation of electrochemically generated radicals in aqueous (and other large dielectric loss) samples and achieves accurate potential control for electrochemistry by using micro-wires as working electrodes. The electrochemical be...
In order to simulate electrochemical reactions in the framework of quantum chemical methods, density functional theory, methods can be devised that explicitly include the electrochemical potential. In this work we discuss a Grand Canonical approach in the framework of density functional theory in which fractional numbers of electrons are used to represent an open system in contact with an elect...
Reversible superconductor-insulator transition in LiTi2O4 induced by Li-ion electrochemical reaction
Transition metal oxides display various electronic and magnetic phases such as high-temperature superconductivity. Controlling such exotic properties by applying an external field is one of the biggest continuous challenges in condensed matter physics. Here, we demonstrate clear superconductor-insulator transition of LiTi2O4 films induced by Li-ion electrochemical reaction. A compact electroche...
With lead-free legislation impacting printed circuit board (PCB) manufacturing, immersion silver (ImAg) finish is adapted as the top finish of copper trace on PCB due to its many advantages. However, it is easy for silver to form electrochemical migration (ECM) in high humid environment, so that the potential bias and spacing between adjacent circuits are limited. In addition, since the thickne...
Thermodynamic analysis and molecular dynamics simulations were conducted to systematically study the size-dependent electrochemical response of solids. By combining the generalized Young-Laplace equation with the popular Butler-Volmer formulation, the direct influence of surface stress on solid film electrochemical reactions was isolated. A series of thermodynamic formulas were developed to des...
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