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We investigated the underlying physical and chemical causes of the improvement of electrochemical activity of the cathode in solid oxide fuel cells (SOFC) under long term cathodic or anodic polarization, termed ‘current conditioning’, through in situ X-ray absorption spectroscopy (XAS). The electrodes were powder La0.8Sr0.2MnO3 (LSM) made with glycine-nitrate process and thin films of LSM and L...

Thin films of the perovskite barium tin oxide (BaSnO3) were prepared and characterized by their structural optical, electrical, and photoluminescent characteristics. Film deposition methods included both RF sputtering and pulsed laser deposition techniques. High quality, oriented films having optical bandgaps ranging between 3.7 eV & 4.4 eV were produced on various substrates. The undoped films...

We present a series of detailed band calculations on the various structural phases of doped lanthanum cuprate: HTT, LTO, and LTT. The LTO distortion is shown to have little effect on the electronic density of states (DOS). A fit to the pressure dependence of the superconducting transition temperature indicates that only 2.5% of the DOS is affected by the HTT→ LTO transition. The LTT distortion ...

Titania, single-doped and lanthanum-silver co-doped titania nanocomposite were coated on cellulosic and polyacrylonitrile fibers via sol–gel method. The prepared samples were evaluated using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), photolumines...