Diethyl l-tartrate (DET) is used as a biobased plasticizer for poly(lactide) (PLA) formulations with improved ductile properties without compromising biodegradation. Different weight percentages (wt.%) of DET in the 0–50 wt.% range are added to PLA by melt compounding and subsequently processed injection molding. The effect on mechanical, thermal, thermo-mechanical, morphology, biodegradation, ...

Supramolecular polymers can substantially influence the dynamic mechanical properties in slightly crosslinked polymer networks. One prominent example of supramolecular building blocks is 2-ureido-4[1H]-pyrimidinones (UPy). Combining UPy-terminated segments with classical covalent-reactive monomers implements behavior photopolymerizable systems. In this work, a UPy-based methacrylic monomer (up ...

Maleic anhydride (MAN) copolymers with methyl methacrylate(MMA), ethyl methacrylate(EMA), methyl acrylate(MA), ethyl acrylate (EA) and buthyl acrylate (BA) ( in a 1:1 mole ratio) were synthesized by free radical polymerizations method under vacuum -azobis(isobutironitrile)(AIBN) as an initiator of reaction at 701C. The copolymer compositions were determined using related 1H NMR spectra techni...

The addition of less than 1 vol%, 33 nm zinc oxide nanoparticles into a polyurethane matrix resulted in approximately 40% decrease in the Young’s modulus, 80% decrease in strain at fracture, and 50% decrease in the storage modulus, but at the same time resulted in an w11 8C increase in the glass transition temperature of the polymer. These results appear to contradict the general principle obse...

nanocomposite vulcunizates based on styrene-butadiene rubber (sbr), organoclay and a conventional sulfur curing system were prepared by melt blending process in an internal mixer. in order to study the effects of the type of interfacial compatibilizer on the properties of sbr and clay nanoparticles,three types of compatibilizers, maleic anhydride grafted ethylene-propylene diene rubber (epdm-g-...

maleic anhydride (man) copolymers with methyl methacrylate(mma), ethyl methacrylate(ema), methyl acrylate(ma), ethyl acrylate (ea) and buthyl acrylate (ba) ( in a 1:1 mole ratio) were synthesized by free radical polymerizations method under vacuum -azobis(isobutironitrile)(aibn) as an initiator of reaction at 701c. the copolymer compositions were determined using related 1h nmr spectra techni...