The fluorescent chiral tagging reagent, 4-(3-isothiocyanatopyrrolidin-1-yl)7-(N,N-dimethylaminosulfonyl)-2,1,3-benzoxadiazole (DBD-PyNCS), was utilized for the resolution of thiol enantiomers as diastereomeric derivatives. The reagent reacts with thiol enantiomers in the presence of pyridine to produce the corresponding dithiocarbamate diastereomers under mild reaction conditions (50 °C for 40 ...

Biferrocene bearing planar metal dithiocarbamates, namely, [M(FcCH2dtc)2] (dtc = furan-2-ylmethyldithiocarbamate, M = Cu(II) 1, Ni(II) 4; dtc = benzo[d][1,3]dioxol-5-ylmethyl dithiocarbamate, M = Cu(II) 2, Ni(II) 5; dtc = pyridin-2-ylmethyldithiocarbamate, M = Cu(II) 3, Ni(II) 6; Fc = ferrocenyl; Fe(η(5)-C5H5)(η(5)-C5H4-)), have been synthesized and characterized by microanalysis, magnetic susc...

In this paper, we introduce a novel and convenient method for the transformation of heterocyclic amides into heteocyclic thioamides. A two-step approach was applied for this transformation: Firstly, we applied a chlorination of the heterocyclic amides to afford the corresponding chloroheterocycles. Secondly, the chloroherocycles and N-cyclohexyl dithiocarbamate cyclohexylammonium salt were heat...

A dithiocarbamate chain transfer agent (CTA) based on Z-group substituted with a diphenyl amine (–NPh2) moiety is selected for the synthesis of statistical and diblock copolymers ethylene vinyl acetate via reversible addition–fragmentation polymerization. Benefiting from good growth control polyethylene (PE), poly(vinyl acetate) (PVAc), poly(ethylene-co-vinyl (EVA) achieved this CTA, linear typ...

Despite the globally increasing use of platinum-based cytostatic drugs in treatment several types cancer, only limited attention has been paid to developing a for contaminated liquid samples originating from hospitals, laboratories and manufacturing facilities before after their administration. In this work, we assess efficiency low-cost adsorbent material, dithiocarbamate-functionalized silica...

introduction: acute renal failure is a common consequence of sepisis due to concurrent renal ischaemia. the role of nitric oxide (no) in endotoxaemia and in ischaemic injury in the kidney is not well defined. material and methods: in this study we have used an animal model of sepsis induced by injection of bacterial lipopolysaccharide (lps) in the rat and measured renal nitric oxide by x-band e...

A review of the coordination chemistry along with structural features heavy element complexes dithiocarbimate di-anions in form [(R)C=NCS2]2− for R = CN, alkyl, and aryl are described. This class compound is far less studied compared well-explored dithiocarbamate mono-anions formulated as [R(R’)NCS2]− R/R’ H, aryl. The dominated by a S,S-chelating mode; rare examples alternative modes evident. ...

background: the aim of this study was to evaluate the radioprotective capacity of some novel aminoalkylated dithiocarbamic acid potassium salts against γ-irradiation in mice. materials and methods: eight compounds containing 2-aminoethyl-, 3- aminopropyl-, 4-aminobutyl-, 5-aminopentyl-, 6- aminohexyl-, 7-aminoheptyl-, 8-aminooctyl and 9- aminononyl of dithiocarbamate derivatives were prepared. ...

Pesticides are used in large amounts in agriculture and the evaluation of their toxic effects is of major concern to public and environmental health. The aim of the present study was to investigate the genotoxic potential of a commercial formulation of the fungicide mancozeb by the micronucleus test in bone marrow and the comet assay in total blood of Wistar rats. Adult male Wistar rats were tr...