A dispersive liquid-liquid microextraction method for the determination of bismuth in various samples by flame atomic absorption spectrometry is described. In this method, crystal violet was used as counter positive ion for BiCl4 (-) complex ion, chloroform as extraction solvent, and ethanol as disperser solvent. The analytical parameters that may affect the extraction efficiency like acidity o...

A very simple, rapid and sensitive dispersive liquid-liquid microextraction (DLLME) followed by gas chromatography and flame ionization detection (GC-FID) was developed for the determination of phenol and carvacrol in honey samples. A mixture of 100 μl dichloromethane (extraction solvent) and 0.5 ml acetonitrile (disperser solvent) was rapidly injected into sample solution. Thereby a cloudy sol...

A simple, rapid, efficient, and environmentally friendly method for the determination of five triazine herbicides in water and soil samples was developed by using dispersive liquid-liquid microextraction (DLLME), coupled with high performance liquid chromatography-diode array detection (HPLC-DAD). The water samples were directly used for DLLME extraction. For soil samples, the target analytes w...

Microextração líquido-líquido dispersiva (DLLME) utilizando líquido iônico (IL) como solvente extrator foi desenvolvida com uma nova abordagem para a determinação de quatro pesticidas piretróides em amostras ambientais de água e solo. Cromatografia líquida de alto rendimento com detector de UV (HPLC-UV) foi empregada na análise cromatográfica. Este método é rápido, fácil de operar e ambientalme...

In the present study, a simple and efficient extraction method based on dispersive liquid-liquid microextraction prior to UV-Vis spectrophotometry was developed for the preconcentration and determination of copper ions in environmental samples. Briefly, cupric ions (Cu II) were reduced to cuprous (Cu I) with addition of hydroxyl amine hydrochloride and formed hydrophobic chelates with neocuproi...

A new method for the analysis of estrogens including estrone (E1), 17b- estradiol (E2) and diethylstilbestrol (DES) in aqueous samples was performed using dispersive liquid liquid microextraction (DLLME) and high- performance liquid chromatography (HPLC). In order to optimize DLLME some important parameters such as type and volume of extraction and disperser solvent, extraction time, ionic stre...

an efficient, rapid, simple, and highly selective dispersive liquid–liquid microextraction basedon solidification of floating organic drop (dllme-sfod), combined with flame atomicabsorption spectrometry was developed for preconcentration and determination of trace amountsof cobalt in water samples. in this method, an appropriate mixture of acetone and1-undecanol was injected rapidly into the aq...