High performance epoxy resin (tetra-glycidyl-4,4’diamino-diphenyl methane-TGDDM) is brittle and is sensitive to moisture absorption and thermooxidative effects. An approach to mitigate polymer sensitivity towards moisture and thermal effects is to add clay. The addition of clay to resin systems (e.g. diglycidyl ether bisphenol A-DGEBA) has often yielded an overall improvement in properties of t...

a r t i c l e i n f o In Soil Taxonomy three diagnostic subsurface horizons reflect clay enrichment: the argillic, kandic, and natric horizons. Clay illuviation is recognized in Soil Taxonomy at some level in 10 of the 12 orders, including the percent of the soil series in the USA contain taxonomically defined clay-enriched horizons. However, many other soils contain Bt horizons that do not qua...

We have developed a green method to reduce graphene oxide via a UV-irradiated photoreduction process in which H(3)PW(12)O(40) was used as photocatalyst. Moreover, H(3)PW(12)O(40) can adsorb on the reduced graphene oxide as anionic stabilizer and lead to water dispersible graphene sheets.

Dispersible microscale mirror particles were synthesized by linkage of citrate-coated gold nanoparticles and 3-aminopropylsilyl-modified Ca2Nb3O10 perovskite nanoplates. The mirror particles reflect 14-19% of light in the 500-800 nm wavelength interval with retention of polarization. Due to their directional reflection properties, laser-irradiated micromirror dispersions in solvents exhibit Bro...

The presence of clay-sized particles and clay minerals in modern sands and ancient sandstones has long presented an interesting problem, because primary depositional processes tend to lead to physical separation of fineand coarse-grained materials. Numerous processes have been invoked to explain the common presence of clay minerals in sandstones, including infiltration, the codeposition of floc...

The past decade has witnessed an explosion of interest in the development of luminescent nanoparticles because of their excellent potentials in biomedical application. Most recently, lanthanide ion (Ln) doped upconversion nanoparticles (UCNPs), typically NaMF4:Yb /Ln (M= yttrium or gadolinium, Ln= erbium or thulium), have become an exciting new class of nanophosphors that convert nearinfrared (...

Clay-based nanostructured multilayers, such as clay-polymer multilayers and clay-oxide multilayers, have attracted growing attention owing to their remarkable mechanical properties and promising application in various fields. In this paper, synthesis of a new kind of nanostructured clay-oxide multilayers by layer-by-layer self-assembly was explored. Nano-mechanical characterization of 18 clay-b...

Composites based on high density polyethylene (HDPE), pine flour, and organic clay were made by melt compounding and then injection molding. The influence of clay on crystallization behavior, mechanical properties, water absorption, and thermal stability of HDPE/pine composites were investigated. The HDPE/pine composites containing exfoliated clay were made by a two-step melt compounding proced...

Pd–N-heterocyclic carbine complex immobilized on magnetic nanoparticles is synthesized and characterized by different techniques such as FT-IR, XPS, TEM, EDX, FESEM, VSM, TGA, ICP. The catalyst was used a new water dispersible heterogeneous in the fluoride-free Hiyama, Suzuki–Miyaura cyanation reactions pure water. By this method, types of biaryls aryl nitriles were good to high yields reaction...