CPL active enantiopure zinc(ii) complexes based on the first tetradentate salen ligands surrounded by [4]helicene moieties and chiral 1,2-cyclohexane-diamine are reported.

In this study the microstructure of alcohol binary mixtures (toluene and cyclohexane) is investigated from molecular dynamics simulations. case cyclohexane mixtures, we show that strong deviation ideality result formation nanophases molecules gathered in aggregates hydrogen bonds leading to spatial heterogeneity. Nanophases disappear as alkyl chain size increases because hydrophobic interaction...

The separation of benzene and cyclohexane azeotrope is one the most challenging processes in petrochemical industry. In this paper, deep eutectic solvents (DES) were used as for cyclohexane. DES1 (1:2 mix tetrabutylammonium bromide (TBAB) levulinic acid (LA)), DES2 TBAB ethylene glycol (EG)) DES3 ChCl (choline chloride) LA) entrainers, vapor-liquid equilibrium (VLE) measurements at atmospheric ...

The study of tautomerics equilibria is vital importance as tautomeric compounds reactivity highly depends on the proportion each tautomer. Herein, equilibrium 3-phenyl-2,4-pentanedione was studied theoretically by b3lyp/6-31+g(d)methods. effect four solvents considered (water, methanol, carbon tetrachloride and Cyclohexane).The takes place through four-membered ring transition state. barrier he...