نتایج جستجو برای: cycloalkanes
تعداد نتایج: 173 فیلتر نتایج به سال:
Filter samples of total suspended particle (TSP) collected during a cruise campaign over the northern South China Sea (SCS) from September to October 2013 were analyzed for non-polar organic compounds (NPOCs) as well as organic carbon (OC), elemental carbon (EC) and water-soluble ions. A total of 115 NPOCs species in groups of n-alkanes, polycyclic aromatic hydrocarbons (PAHs), iso-/antiso-alka...
The Deepwater Horizon oil spill produced large subsurface plumes of dispersed oil and gas in the Gulf of Mexico that stimulated growth of psychrophilic, hydrocarbon degrading bacteria. We tracked succession of plume bacteria before, during and after the 83-day spill to determine the microbial response and biodegradation potential throughout the incident. Dominant bacteria shifted substantially ...
Motor oil serves as a useful model system for atmospheric oxidation of hydrocarbon mixtures typical of anthropogenic atmospheric particulate matter, but its complexity often prevents comprehensive chemical speciation. In this work we fully characterize this formerly "unresolved complex mixture" at the molecular level using recently developed soft ionization gas chromatography techniques. Nuclea...
We develop the idea that the use of ad hoc molecular descriptors in QSAR/QSPR studies is not an optimal solution. Instead, we propose to optimize these descriptors for the specific properties under study. In the case of topological indices (TIs) we propose the use of the generalized topological indices (GTIs), which account for several of the classical TIs in one single graph invariant. GTIs re...
Alkylated cycloalkanes are vital components in gasoline, aviation, and diesel fuels; however, their combustion chemistry has been less investigated compared to other hydrocarbon classes. In this work, the kinetics of n-propylcyclohexane (n-Pch) was studied across a range experiments including pressurized flow reactor (PFR), jet stirred (JSR), shock tube (ST), rapid compression machine (RCM). Th...
The purpose of the present work is to show that light straight-run gasoline fraction can be used as feedstock for hydro-catalytic isomerization process, and isomerized product serve a component obtaining pure ecological commercial brand Euro-4 Euro-5. Transformation n-alkanes Zhanazhol oil’s with boiling temperature 180°C was studied. Isomerization carried out in flow unit stationary layer modi...
Vehicle traffic pollution requires complex physicochemical analysis besides emission level measuring. The current study is focused on two campaigns of emissions measurements held in May and September 2019 Alba Iulia City, Romania. There was found a significant excess PM2.5 for all measuring points PM10 the most circulated during May, along with VOC CO2 emissions. reveal threshold PM increased v...
Abstract The complex application of modern analysis methods (FT-IR, NMR, GC–MS and UV/Vis) allowed us to study in detail the composition crude Surakhani light oil with a composition. An accurate comprehensive oils makes it easier find necessary field for them. For this purpose, studied was separated into two fractions, such as paraffinic–naphthenic aromatic (groups 1st, 2nd, 3rd tar), by absorp...
This work reports a theoretical study of the gas phase unimolecular decomposition of cyclobutane, cyclopentane and cyclohexane by means of quantum chemical calculations. A biradical mechanism has been envisaged for each cycloalkane, and the main routes for the decomposition of the biradicals formed have been investigated at the CBSQB3 level of theory. Thermochemical data (H°f, S°, C°p) for all...
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