The heteronuclear [Na(2)Cu(4)(bemp)(2)(OH)(2)(NO(3))(2)(OH(2))(4)] x 5 H(2)O (1 x 5H(2)O; H(3)bemp: 2,6-bis-[(2-hydroxyethylimino)-methyl]-4-methyl-phenol) cluster has been synthesized in aqueous-methanol at room temperature and structurally characterized. The water soluble complex is obtained from the template assembly of two [Cu(2)(bemp)(OH)] neutral fragments through their weak oxophillic in...

We report here the crystal structure of yeast copper thionein (Cu-MT), determined at 1.44-A resolution. The Cu-MT structure shows the largest known oligonuclear Cu(I) thiolate cluster in biology, consisting of six trigonally and two digonally coordinated Cu(I) ions. This is at variance with the results from previous spectroscopic determinations, which were performed on MT samples containing sev...

A novel label-free colorimetric strategy was reported for sensitive detection of copper ions (Cu(2+)) by using the decelerating etching of gold nanorods (GNRs). H2O2 was employed as the oxidant for corrosion of GNRs, leading to the decrease of the aspect ratio of GNRs. In the absence of Cu(2+), the redox corrosion of GNRs by H2O2 occurred rapidly, causing the distinct color change of GNRs from ...

A study on the propane gas-sensing properties of Cu-doped ZnO thin films is presented in this work. The films were deposited on glass substrates by sol-gel and dip coating methods, using zinc acetate as a zinc precursor, copper acetate and copper chloride as precursors for doping. For higher sensitivity values, two film thickness values are controlled by the six and eight dippings, whereas for ...

The Menkes protein (ATP7A) is defective in the Cu deficiency disorder Menkes disease and is an important contributor to the maintenance of physiological Cu homeostasis. To investigate more fully the role of ATP7A, transgenic mice expressing the human Menkes gene ATP7A from chicken beta-actin composite promoter (CAG) were produced. The transgenic mice expressed ATP7A in lung, heart, liver, kidne...

Twelve male 8-month-old lambs were used in a 6-month feeding experiment to determine the effects of dietary Mo, Mo + S and Zn supplements on the body retention and tissue accumulation of dietary Cu, Zn and Fe. The lambs were divided into four groups of three lambs each and each group was fed ad libitum one of four diets. A control diet was based on palm kernel cake (PKC) and grass hay. Three ad...

Thermal conductivity, K, of two ceramic samples of T12Ba2Ca2Cus0,c has been measured over a ten-Zerature range from 300 K down to 0.1 K. At high temperatures, the data show features similar to the thermal conductivity of Y-Ba-Cu-0 and Bi-Sr-CaCu-0 ceramics in both the magnitude and the temperature dependence. Specifically, a sudden increase in the thermal conductivity is observed at the onset o...

High energy (100-400 keV) scanning electron microscope (SEM) imaging of samples can be performed in the transmission electron microscope (TEM)/scanning TEM (STEM) when the system has secondary electron (SE) and/or backscattered (BSE) electron detector(s) installed. Previously, very high resolution SE imaging has been demonstrated at 200 keV in a STEM with a spherical aberration corrected conden...

The evolution of microstructure in MO-Cu thin films during annealing has been investigated by in situ sheet resistance measurements, ex situ x-ray diffraction, and ~PZ situ hot-stage as well as conventional transmission electron microscopy. MO-Cu thin films, deposited on various glass substrates by magnetron sputtering at -30 “C, were supersaturated solid solutions of Cu in MO with a nanocrysta...

 Concentration of heavy and toxic metals Cu, Zn, Cd, Pb and Hg were determined in liver and muscles of Rutilus frisii kutum and their relationships with growth parameters (length, age, condition factor) and hepatosomatic index were examined. Thirty-six fish samples were collected from February through March 2009 caught by beach seine in the southwest parts of the Caspian Sea. Atomic absorption ...