نتایج جستجو برای: covalent bulk polymerization
تعداد نتایج: 123703 فیلتر نتایج به سال:
Effect of vitamin A compounds on the covalent binding of benzo(a)pyrene [B(a)P] to subnuclear components was studied using rat liver nuclei in vitro. The retinol-induced inhibition of the covalent binding of B(a)P depended both on the dose and the time of addition. Retinal and retinyl acetate were both potent inhibitors, but retinoic acid was less effective. Retinol induced marked inhibition of...
The design of crosslinking domains is a vital factor to create functional hydrogels with controlled physical, mechanical, and adhesive properties. This paper demonstrates versatile synthetic systems micelle-crosslinked highly stretchable, self-healing, selectively For this, methacrylate-bearing random copolymer micelles are designed as physical covalent crosslink via the self-assembly amphiphil...
BACKGROUND The aim of present study was to develop the novel methods for chemical and physical modification of superparamagnetic iron oxide nanoparticles (SPIONs) with polymers via covalent bonding entrapment. These modified SPIONs were used for encapsulation of anticancer drug doxorubicin. METHOD At first approach silane-grafted magnetic nanoparticles was prepared and used as a template for ...
polymerization are negatively charged in a broad pH range The aim of the present work is to prepare and characterize of 3–10 (4), but their surface charge density is extremely carboxylated latexes (CLs) in order to bind antibodies covalently high (4). At a low ionic strength the antibody cannot peneand efficiently. Carboxylated latexes were prepared by surfactanttrate the double layer of the pa...
Objectives: The aim of this study was to compare polymerization depth of two bulk-fill and one conventional composite cured for different times. Methods: This in vitro experimental study was conducted on 54 composite samples (2×4×10mm) fabricated of Tetric N-Ceram bulk-fill, x-tra fil bulk-fill, and Grandio conventional composite cured for 20, 30, and 40 seconds. The microhardnes...
The charge distribution in atoms with closed electron shells is spherically symmetric, whereas atoms with partially filled shells can form covalent bonds with pointed lobes of increased charge density. Covalent bonding in the bulk can also affect surface atoms, leading to four tiny humps spaced by less than 100 picometers in the charge density of adatoms on a (001) tungsten surface. We imaged t...
Photoinitiated thiol–ene polymerization was performed in bulk and miniemulsion. We show that the compartmentalization of reaction inside nanodroplets led to faster kinetics yielded polymers with higher molecular weight.
in atom transfer radical polymerization (atrp) of methyl acrylate (ma) with polyvinyl acetate macroinitiator in bulk at 90°c the plots of ln [m]0/[m] increased linearly with reaction time. the apparent propagation rate constant (kp app) of the reaction was obtained from the linear curve and used to calculate the free macroradical concentration ([r°]) in polymerization medium. the [r°] and also ...
An orthorhombic (space group Pnnm) boron phase was synthesized at pressures above 9 GPa and high temperature, and it was demonstrated to be stable at least up to 30 GPa. The structure, determined by single-crystal x-ray diffraction, consists of B12 icosahedra and B2 dumbbells. The charge density distribution obtained from experimental data and ab initio calculations suggests covalent chemical b...
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