Reactive separations of CO/CO2 mixtures are a promising pathway to lower the energy requirement CO2 hydrogenation chemicals and fuels, with applications in U.S. Navy’s seawater-to-fuel process. With feedstock, challenge is activating CO produce heavier hydrocarbons while preventing methanation, requiring low-temperature Fischer-Tropsch synthesis (FTS) catalysts. In this work, we demonstrate tha...

CO2 emissions from combustion flue gases have turned into a major factor in global warming. Post-combustion carbon capture (PCC) from industrial utility flue gases by reactive absorption can substantially reduce the emissions of the greenhouse gas CO2. To test a new solvent (AIT600) for this purpose, a small pilot plant was used. This paper presents the results of studies ...

Six new complexes of the type trans-[LCo((DO)(DOH)pn)L'] where (DO)(DOH)pn= N2, N2'-propanediolbis (2,3-butanedione 2-imine 3-oxime), L-Cl¯ and L'=mono-anaion of phenylcyanamide (pcyd), 2,5-dichlorophenylcyanamide (2,5-Cl2 pcyd), 2,4-dimethyl pehylcyanamide (2,4-Me2 pcyd) and L=L'=pcyd, 2,5-Cl2 pcyd, 2,4-Me2 pcyd, have been s...