In this work, we present the application of exergy analysis in the evaluation of the ethanol steam reforming (ESR) process in a catalytic membrane reactor (CMR) containing Pd-Ag membranes sandwiched by PdRh/CeO2 catalyst to produce fuel cell grade pure hydrogen (no sweep gas). ESR experiments were performed at T=873-923 K and P=4-12 bar. The fuel was a mixture of ethanol and distilled water wit...

Operando 5D X-ray diffraction imaging reveals complex heterogeneities across multiple length scales in a catalytic reactor for the partial oxidation of methane reaction.

CoSi particles on a silica support, synthesized by metal organic chemical vapor deposition (MOCVD) of Co(SiCl(3))(CO)(4) as a precursor at atmospheric pressure and moderate temperature in a fluidized bed reactor, show high catalytic activity and selectivity in naphthalene hydrogenation.

Fluorescent aggregates formed by self-assembly of a hexaphenylbenzene based derivative serve as a reactor and a stabilizer for the formation of ferromagnetic iron oxide (α-Fe2O3) nanoparticles in aqueous medium at room temperature. These α-Fe2O3 nanoparticles showed excellent catalytic activity in palladium, copper and amine free Sonogashira cross coupling reactions and also in photocatalytic d...

X-Ray absorption spectra show that a CeO(2)-supported CO oxidation catalyst prepared from Au(III)(CH(3))(2)(C(5)H(7)O(2)) initially incorporated Au(III) complexes that were catalytically active at 353 K; during operation in a flow reactor, the gold aggregated into clusters and the catalytic activity increased.

In this study of catalytic microfluidic reactors we show that, when optimally structured, these reactors share underlying scaling properties. The scaling is predicted theoretically and verified numerically. Furthermore, we show how to increase the reaction rate significantly by distributing the active porous material within the reactor using a high-level implementation of topology optimization.

A fluidized bed reactor that is operating in the bubbling regime has been developed for the conversion of bio-oils to syngas.The reactor consists of a 7.6 cm I.D. (or internal diameter) bed, with an expanded freeboard. The volume of the reactor can be adjusted to vary the gas residence time. This reactor has been used to carry out either thermal or catalytic cracking for reforming bio-oils.A ga...

Determination of metal oxidation state under relevant working conditions is crucial to understand catalytic behaviour. The reduction behaviour of Pt and Re was evaluated simultaneously as a function of support and solvent in a pressurized reactor (autoclave). The bimetallic catalysts are used in selective hydrogenation of carboxylic acids and amides. Gas phase reduction reduced the metals more ...

A multi-phase flow strategy, based on oscillatory motion of a bi-phasic slug within a fluorinated ethylene propylene (FEP) tubular reactor, under inert atmosphere, is designed and developed to address mixing and mass transfer limitations associated with continuous slug flow chemistry platforms for studies of bi-phasic catalytic reactions. The technique is exemplified with C-C and C-N Pd catalyz...

A series of substituted aliphatic nitriles have been trimerized to their corresponding pyrimidine structures under solvent-free conditions in the presence of catalytic quantities of potassium tert-butoxide using a focused microwave reactor. Multigram quantities of the corresponding 4-aminopyrimidines have been prepared in high yields and purity following a simple and scaleable protocol.