نتایج جستجو برای: carbonyl compound

تعداد نتایج: 139449  

Journal: :Dalton transactions 2010
Lindsay Hewison Sian H Crook Tony R Johnson Brian E Mann Harry Adams Sarah E Plant Philip Sawle Roberto Motterlini

New CO-releasing molecules, CO-RMs, based on indenyl iron carbonyls have been identified. Half-lives for carbon monoxide (CO) release, (1)H NMR, (13)C NMR, IR, mass spectra, elemental analysis and biological data have been determined for the compounds. Limited correlations have been made between half-lives and ΔG(‡) for CO release and spectroscopic parameters, ν(CO) and δ((13)CO). X-ray structu...

Journal: :Dalton transactions 2016
Paul Shaw Alan R Kennedy David J Nelson

The synthesis and co-ordination chemistry of a new 'bulky yet flexible' N-heterocyclic carbene ("IPaul") is reported. This carbene has spatially-defined steric impact; steric maps show that two quadrants are very bulky while the other two are quite open. The electronic properties of this carbene are very similar to those of other 1,3-diarylimidazol-2-ylidenes. Copper, silver, iridium, and nicke...

2003
Anant Prakash Devjani Adhikari

Schiff bases are versatile ligands which are synthesized from the condensation of an amino compound with carbonyl compounds. These compounds and their metal complexes are very important as catalysts in various biological systems, polymers, dyes and medicinal and pharmaceutical fields. Their use in birth control, food packages and as an O2 detector is also outlined. This review summarizes the ap...

Journal: :Chemical communications 2011
Kristine Müther Martin Oestreich

The silylium ion-catalysed reduction of carbonyl compounds to the alcohol oxidation level is accomplished by exploiting the unique reactivity of a ferrocenyl-substituted silane.

Journal: :Molecules 2014
David W Manley Luca Buzzetti Andrew MacKessack-Leitch John C Walton

A mild procedure for the reduction of electron-deficient alkenes and carbonyl compounds is described. UVA irradiations of substituted maleimides with dispersions of titania (Aeroxide P25) in methanol/acetonitrile (1:9) solvent under dry anoxic conditions led to hydrogenation and production of the corresponding succinimides. Aromatic and heteroaromatic aldehydes were reduced to primary alcohols ...

Journal: :Organic letters 2002
Jesse D More Nathaniel S Finney

[reaction: see text] An efficient, user-friendly procedure for the oxidation of alcohols using IBX is described. Simply heating a solution of the alcohol in the presence of suspended IBX followed by filtration and removal of the solvent gives excellent yields of the corresponding carbonyl compounds. We illustrate this procedure with a panel of primary and secondary alcohol substrates and note t...

Journal: :Chemical communications 2013
Lu Gao Ji Lu Zhenlei Song Xinglong Lin Yongjin Xu Zhiping Yin

An unusual [1,5]-Brook rearrangement of the lithium alkoxide of geminal bis(silyl) homoallylic alcohol is described. The unique steric and electronic effects of geminal bis(silane) were found to be crucial for promoting this long-range silyl migration, as well as for facilitating the subsequent γ/Z-selective addition of silyl allyllithium with carbonyl compounds to synthesize diverse configurat...

Journal: :Organic letters 2002
Zhiyong Wang Zhenggen Zha Cunliu Zhou

[reaction: see text] Nanometer tin-mediated allylation of aldehydes or ketones in distilled or tap water gave rise to corresponding homoallyl alcohol in high yield without any other assistance such as heat or supersonic or acidic media.

2013
Joanna V. Geden Benjamin O. Beasley Guy J. Clarkson Michael Shipman

2-Substituted azetidin-3-ones can be prepared in good yields and enantioselectivities (up to 85% ee) by a one-pot procedure involving the metalation of the SAMP/RAMP hydrazones of N-Boc-azetidin-3-one, reaction with a wide range of electrophiles, including alkyl, allyl, and benzyl halides and carbonyl compounds, followed by hydrolysis using oxalic acid.

Journal: :Organic letters 2005
Weifeng Shi Bo Zhang Jian Zhang Binge Liu Shiwei Zhang Jianbo Wang

[reaction: see text] 1,3 C-H insertion has been found to be a predominant reaction pathway in the Rh(II)-mediated reaction of beta-tosyl alpha-diazo carbonyl compounds.

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