In the present study, conversion performance of hydrogen sulfide (H2S) to elemental sulfur in ionic-liquid-incorporated transition metals (ILTMs) is predicted using a conductor-like screening model for realistic solvents (COSMO-RS). The predictions were made via establishment correlation between and solubility H2S ionic liquids (ILs). All molecules involved optimized at DFT/TZVP/M06 computation...

High quantum yield (47%) InP nanocrystals can be prepared without the need for post HF treatment by combining microwave methodologies with the presence of a fluorinated ionic liquid. Growing the InP nanocrystals in the presence of the ionic liquid 1-hexyl-3-methyl-imidazolium tetrafluoroborate (hmim BF4) allows in situ etching to be achieved. The optimization of the PL QY is achieved by balanci...

The separation of aromatic and aliphatic hydrocarbons is challenging, due to overlapping boiling points and formation of several azeotropes. Conventional solvents for those separations are polar substances, e.g. sulfolane. Recently it could be shown that ionic liquids can perform considerably better than common extraction solvents. Hence, ionic liquids can be a promising alternative [1]. Ionic ...

The Brønsted-acidic ionic liquid 1-methyl-3-(4-sulfobutyl)imidazolium triflate [BMIM(SO(3)H)][OTf] was demonstrated to act efficiently as solvent and catalyst for the halogenation of activated organic compounds with N-halosuccinimides (NXS) under mild conditions with short reaction times. Methyl aryl ketones were converted into α-halo and α,α-dihaloketones, depending on the quantity of NXS used...

The effect of the ionic liquid 1-butyl-3-methylimidazolium chloride ([bmim]Cl) and of high pressure on the activity of cellulase from Aspergillus niger were studied separately and in combination. The enzyme activity decreased with increasing concentrations of [bmim]Cl, reaching 50% the value in aqueous buffer with 20% [bmim]Cl. However, when the enzyme is held in 10% [bmim]Cl and is then assaye...

Photochemical properties of the ionic liquid (RTIL) 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] and its binary mixed solutions with organic solvent (DMF and MeCN) were investigated by laser photolysis at an excitation wavelength of 355 nm, using anthraquinone (AQ) as a probe molecule. It was indicated that the triplet excited state of AQ (AQ*) can abstract hydrogen from [bmim][P...

Ion association of the ionic liquid [bmim][Cl] in acetonitrile and in water was studied by dielectric spectroscopy for salt concentrations c r 1.3 M at 298.15 K and by measurement of molar electrical conductivities, L, of dilute solutions (c r 0.006 M) in the temperature range 273.15 t T/K r 313.15. Whilst acetonitrile solutions of [bmim][Cl] exhibit moderate ion pairing, with an association co...

By using natural softwood pulp with higher degree of polymerization (DP=1460)as cellulose source and 1-butyl-3-methylimidazolium chloride([BMIM]Cl)ionic liquid as solvent, a novel cellulose packaging film was prepared. The effects of coagulation types, concentration of coagulation and temperature on the structure, mechanical property, permeability for oxygen and water vapor were measured. The i...

This work has established the optimum reaction conditions in a biphasic system using microcrystalline cellulose as the raw material, an ionic liquid as the solvent, metal chloride as a catalyst, and an organic solvent as the extraction reagent. The optimum reaction conditions were microcrystalline cellulose:ionic liquid 1:10 (mass ratio), chromium(III) chloride (CrCl3) 6.8 mol% (based on the gl...

Molecular dynamics simulations were performed to address the permeability of defectless alkanethiol self-assembled monolayers (SAMs) on charged and uncharged Au(111) surfaces in 1-butyl-3-methylimidazolium ([bmim][BF4]) room-temperature ionic liquid (IL). We demonstrate that ionic permeation into the monolayer does not start until a critical surface charge density value is attained (both for po...