The dependencies on strain and oxygen vacancies of the ferroelectric polarization and the weak ferromagnetic magnetization in the multiferroic material bismuth ferrite, BiFeO3, are investigated using first principles density functional theory calculations. The electric polarization is found to be rather independent of strain, in striking contrast to most conventional perovskite ferroelectrics. ...

One emergent property of ferroelectric nanoparticles is the sized-induced structural distortion to a high-symmetry paraelectric phase at small particle sizes. Finite length scale effects can thus be advantageously employed to elucidate ferroelectric transition mechanisms. In this work, we combine infrared spectroscopy with group theory and lattice dynamics calculations to reveal the displacive ...

There is a growing activity in the search of novel single-phase multiferroics that could finally provide distinctive magnetoelectric responses at room temperature, for they would enable a range of potentially disruptive technologies, making use of the ability of controlling polarization with a magnetic field or magnetism with an electric one (for example, voltage-tunable spintronic devices, unc...

Understanding the elastic response on the nanoscale phase boundaries of multiferroics is an essential issue in order to explain their exotic behaviour. Mixed-phase BiFeO3 films, epitaxially grown on LaAlO3 (001) substrates, have been investigated by means of scanning probe microscopy to characterize the elastic and piezoelectric responses in the mixed-phase region of rhombohedral-like monoclini...

Herein, the BiFeO3 was modified by substituting varying manganese (Mn) concentration to improve efficacy of eliminating methyl orange (MO), a water-soluble carcinogenic azo dye presented. To examine structure, morphology and band gap characteristics as-synthesised Mn-BiFeO3 nanocatalyst were characterised using various techniques including XRD, FESEM with EDX, FTIR, UV-vis DRS, BET. Subsequentl...

The rheological and tape casting behavior of ethanol-based Bi0.5(Na0.80K0.20)0.5TiO3-7 mol% BiFeO3 (BNKT-BF) slurries was investigated. The effect of sintering temperature profile on texture development with a preferred orientation was also studied. A 50 MPa pressure assisted three step sintering profile promoted extensive texture development together with densification. The role of BF as a sin...

The northwestern Himalayas (NWH) in India have low rice productivity (∼2 t ha −1 ) and quality due to poor crop nutrient management predominantly Zn-deficient soils. Hence, a field experimentation the NWH compared conventionally transplanted (CTR) system of intensification ( SRI) under three practices (NMPs), viz ., 1) farmers’ fertilization practice, FYM @ 5 + N:P 2 O :K 50:40:20 kg (FFP); 2) ...

The present work demonstrates the synthesis and application of permanent magnetic Nd2Fe14B microparticle (NMP)-loaded graphitic inks for realizing rapidly self-healing inexpensive printed electrochemical devices. The incorporation of NMPs into the printable ink imparts impressive self-healing ability to the printed conducting trace, with rapid (~50 ms) recovery of repeated large (3 mm) damages ...

The use of statistical complexity metrics has yielded a number of successful methodologies to differentiate and identify signals from complex systems where the underlying dynamics cannot be calculated. The Mori-Zwanzig framework from statistical mechanics forms the basis for the generalized non-Markov parameter (NMP). The NMP has been used to successfully analyze signals in a diverse set of com...