IN THE TITLE COMPOUND [SYSTEMATIC NAME: N-(carbamoyl-carb-a-mo-thio-yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio-biuret groups are almost coplanar, making a dihedral angle of 8.48 (5)°. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen bo...

The title mol-ecule, C(16)H(24)N(2)OS, is twisted about the central N(H)-C bond with a C-N(H)-C-N torsion angle of -62.67 (15)°. The carbonyl group is twisted out of the plane of the benzene ring, forming a C-C-C=O torsion angle of -25.06 (17)°. In the crystal, mol-ecules related by centres of symmetry are linked by pairs of inter-molecular N-H⋯S hydrogen bonds, forming eight-membered {⋯HNCS}(2...

In the title compound, C(14)H(12)N(2)O(2), the mol-ecular conformation is determined by a strong intra-molecular N-H⋯O=C hydrogen bond. In the crystal, pairs of mol-ecules are connected by inter-molecular N-H⋯O=C hydrogen bonds, forming centrosymmetric dimers. No specific inter-actions between dimers could be found.

The present research describes the synthesis of novel 5-benzoyl-N-substituted-amino- and 5-benzoyl-N-sulfonylamino-4-alkylsulfanyl-2-pyridones 5a-c and 6a-c via the reaction of 2-benzoyl-3,3-bis(alkylthio)acrylonitriles 2a-c with N-cyanoacetohydrazide 3 and cyanoaceto-N-phenylsulfonylhydrazide 4, respectively. Also, the reactivity of the compounds 5a-c toward hydrazine hydrate to give product 1...

Purified isothiocyanates from cruciferous plants (Brassicacea, Syn. Cruciferae) plants were evaluated against 15 isolates of methicillin-resistant S. aureus isolated from diabetic foot-ulcer patients aiming the study of the potential usage of allyl-isothiocyanate, benzyl-isothiocyanate and 2-phenylethyl-isothiocyanate against this important bacteria. Disc diffusion and minimum inhibitory concen...