BACKGROUND Mesenchymal stromal cells (MSCs) have an inherent migratory capacity towards tumor tissue in vivo. With the future objective to quantify the tumor homing efficacy of MSCs, as first step in this direction we investigated the use of inorganic nanoparticles (NPs), in particular ca. 4 nm-sized Au NPs, for MSC labeling. Time dependent uptake efficiencies of NPs at different exposure conce...

Gold nanoparticles (Au NPs)@ZnO nanorods (NRs) hybrids, with various molar ratios of ZnO:Au, were developed to enhance generation of reactive oxygen species (ROS) for further application in photodynamic therapy (PDT). By introducing the metal/semiconductor heterostructure interface between Au NPs and ZnO NRs, the electron transfer was modulated under UV irradiation, which dramatically suppresse...

We determined the surface-enhanced Raman scattering of the plasmonic hybrid nanotubes of fullerene C60-polythiophene-Ag or Au nanoparticles (NPs) which were synthesized via the template-based electrocopolymerization of terthiophene-linked fullerene C60 and terthiophene-modified Ag NPs or Au NPs using a nanoporous alumina membrane as the template. The combination of plasmonic activity and chemic...

A method was developed for the synthesis of molecularly imprinted Au nanoparticle (NP) composites on electrodes by electrochemical means. The resulting composites include specific recognition sites for mono- or disaccharides. The method is based on the formation of a boronate complex between the respective saccharide and the boronic acid ligands associated with the Au NPs. The electropolymeriza...

Homogeneous immobilization of gold nanoparticles (Au NPs) on mesoporous silica has been achieved by using a one-pot synthesis method in the presence of organosilane mercapto-propyl-trimethoxysilane (MPTMS). The resultant Au NPs exhibited an excellent catalytic activity in the solvent-free selective oxidation of cyclohexane using molecular oxygen. By establishing the structure-performance relati...

The interaction between semiconductor nanowires (NWs) and metallic nanocolloids were studied upon bioconjugation of two biomaterials: d-biotin and streptavidin. 5-fold intensity enhancement of luminescence and a blue shift of the emission peak were observed after conjugation with Au NPs. It can be interpreted in terms of the electromagnetic field enhancement effect in the presence of metallic N...

by Lisa E. Cole Breast cancer is the most common cancer and the second leading cause of cancerrelated deaths among women. Early detection is considered the best option for reducing morbidity and mammography is the current gold standard for early detection of breast cancer. Microcalcifications are the most common abnormality observed on a mammogram and are early markers for breast cancer. Howeve...

This work has mainly investigated the influence of the solvent on the nanoparticles distribution in digestive ripening. The experiments suggested that the solvents played a key role in digestive ripening of Au nanoparticles (Au NPs). For the benzol solvents, the resulting size distribution of Au NPs was inversely related to the solvent polarity. It may be interpreted by the low Gibbs free energ...

Herein we explore the role of localized plasmonic heat generated by resonantly excited gold (Au) NPs on visible light driven photocatalysis process. Au NPs are deposited on the surface of vertically aligned zinc oxide nanorods (ZnO NRs). The localized heat generated by Au NPs under 532 nm continuous laser excitation (SPR excitation) was experimentally probed using Raman spectroscopy by followin...

Here we demonstrate that the photoactivity of Au-decorated TiO2 electrodes for photoelectrochemical water oxidation can be effectively enhanced in the entire UV-visible region from 300 to 800 nm by manipulating the shape of the decorated Au nanostructures. The samples were prepared by carefully depositing Au nanoparticles (NPs), Au nanorods (NRs), and a mixture of Au NPs and NRs on the surface ...