Imperfect representation of vertical mixing near the surface in atmospheric transport models leads to uncertainties in modelled tracer mixing ratios. When using the atmosphere as an integrator to derive surface-atmosphere exchange from mixing ratio observations made in the atmospheric boundary layer, this uncertainty has to be quantified and taken into account. A comparison between radiosondede...

Molecular distributions and stable carbon isotopic compositions (δ(13)C) of n-alkanes, fatty acids and n-alcohols were investigated in urban aerosols from Beijing, northern China to better understand the sources and long-range atmospheric transport of terrestrial organic matter during polluted and clear days in winter. n-Alkanes (C19-C36), fatty acids (C8-C32) and n-alcohols (C16-C32) detected ...

Detailed airborne, surface, and subsurface chemical measurements, primarily obtained in May and June 2010, are used to quantify initial hydrocarbon compositions along different transport pathways (i.e., in deep subsurface plumes, in the initial surface slick, and in the atmosphere) during the Deepwater Horizon oil spill. Atmospheric measurements are consistent with a limited area of surfacing o...

Historic and current use pesticides (HUPs and CUPs), with respect to use in the United States and Canada, were identified in trans-Pacific and regional air masses at Mt. Bachelor Observatory (MBO), a remote high elevation mountain in Oregon's Cascade Range located in the United States, during the sampling period of April 2004 to May 2006 (n = 69), including NASA's INTEX-B campaign (spring 2006)...

Coupling of local chemical processes over the globe by atmospheric transport leads to the existence of chemical modes that are a fundamental characterization of global atmospheric chemistry and provide a true description of the atmospheric response to small changes in trace-gas emissions. Such coupled chemistry-transport modes in global tropospheric chemistry are an inherent feature of three-di...

We present a new global three-dimensional chemical model for the troposphere, named CHASER (CHemical AGCM for Study of atmospheric Environment and Radiative forcing). This model, developed in the framework of Center for Climate System Research/National Institute for Environment Studies (CCSR/NIES) atmospheric general circulation model (AGCM), is aimed to study tropospheric photochemistry and it...

Atmospheric concentrations of organochlorine pesticides (OCPs) have been measured for the first time at Station Nord, North-East Greenland, from 2008 to 2010. The data obtained are reported here. Hexachlorobenzene (HCB), endosulfan I and hexachlorocyclohexanes (HCHs) were the predominant compounds detected in the atmosphere, followed by p,p'-DDE and dieldrin. Chlordane isomers and related compo...

For the past 200 years, the field of aerobiology has explored the abundance, diversity, survival and transport of micro-organisms in the atmosphere. Micro-organisms have been explored as passive and severely stressed riders of atmospheric transport systems. Recently, an interest in the active roles of these micro-organisms has emerged along with proposals that the atmosphere is a global biome f...

The HIAPER Pole-to-Pole Observations (HIPPO) programme has completed three of five planned aircraft transects spanning the Pacific from 85 ° N to 67 ° S, with vertical profiles every approximately 2.2 ° of latitude. Measurements include greenhouse gases, long-lived tracers, reactive species, O(2)/N(2) ratio, black carbon (BC), aerosols and CO(2) isotopes. Our goals are to address the problem of...