At high temperatures, the experimental gasification rates of graphitized carbon rods are found to deviate progressively more from their intrinsic gasification rates, aa temperature is increased. This is shown to be caused by the increasing control of the reaction by the rate of transport of carbon dioxide through the internal pores of the carbon rod. The ditTusionalresistance concepts used to c...

X-ray photoelectron and high resolution electron energy loss spectroscopic (XPS-HREELS) studies have shown that the adsorption of carbon dioxide at Mg(100) surfaces at 80K is followed by a dissociative reaction leading to the formation of a metastable surface carbonate above 80K. The formation of a carbonate species is proposed to proceed through oxidation of C0 (g) by an active oxygen su...

The relationship between malic acid production and carbon assimilation was examined in the submerged aquatic Crassulacean acid metabolism (CAM) plant, Isoetes howellii Engelmann. Under natural conditions free-CO(2) level in the water was highest at 0600 hours and (14)CO(2) assimilation rates in I. howellii were also highest at this time. After 0900 hours there was a similar pattern in (a) rate ...

Cerebral venous outflow and carbon dioxide transients were studied during five different transitional states: (1) on and off 10% carbon dioxide breathing, (2) on and off hyperventilation, (3) on 7% carbon dioxide breathing, (4) on 10% carbon dioxide breathing initiated from 7% carbon dioxide breathing, and (5) on 10% carbon dioxide breathing initiated during intracarotid papaverine infusion, in...

A mechanistic model was developed for predicting carbon dioxide corrosion rates of carbon steel pipes in multiphase flow conditions. The model incorporates the chemistry, thermodynamics of carbon dioxide dissolution, multiphase mass transfer, electrochemical kinetics on the metal surface and the presence of a corrosion product film. The predicted corrosion rates show good agreement with the exp...

Ocean acidification is the lowering of pH in the oceans as a result of increasing uptake of atmospheric carbon dioxide. Carbon dioxide is entering the oceans at a greater rate than ever before, reducing the ocean's natural buffering capacity and lowering pH. Previous work on the biological consequences of ocean acidification has suggested that calcification and metabolic processes are compromis...

1. Carbon dioxide-bicarbonate mixtures markedly inhibited oxidation and phosphorylation rates of mitochondria prepared from cauliflower. Inhibition occurred with succinate, malate, citrate, isocitrate and NADH as substrates. 2. Indophenol-reductase systems with malate, succinate, isocitrate and NADH as substrates were inhibited by 5% and 15% carbon dioxide. Cytochrome c oxidase was not inhibite...

BACKGROUND Carbon dioxide concentration under ophthalmic drapes increases during eye surgery under local anaesthesia. A new prototype has been designed which combines continuous suction of carbon dioxide enriched air and continuous oxygen insufflation under ophthalmic drapes to prevent carbon dioxide accumulation in spontaneously breathing patients undergoing cataract surgery. METHODS In a pr...