the reaction of pbci, with 1,4,10,13-tetra-oxa-7, 16-diaza-cyclooctadecane (l= c h n o ) yielded colourless crystals of lpbci . the complex crystallizes in monoclinic space group, c2/c, a = 7.90(2), b = 14.75(3) and c = 17.36(3) ?= ? 101.75(3)?, z = 4 and r = 0.083 the coordination number around the lead atom is eight . [pb-n, 2.36(1), 2.70(4)], [pb-0,2.41(3)-2.57(3)], [pb-ci, 2.51(4), 2.57(4)].