LaCl₃ doped polycrystalline SnSe was synthesized by combining mechanical alloying (MA) process with spark plasma sintering (SPS). It is found that the electrical conductivity is enhanced after doping due to the increased carrier concentration and carrier mobility, resulting in optimization of the power factor at 750 K combing with a large Seebeck coefficient over 300 Μvk-1. Meanwhile, all the s...

The vast majority of steel weld deposits solidify under highly nonequilibrium cooling conditions. A consequence of this is the chemical segregation of substitutional alloying elements during solidification, a segregation that persists as the weld cools to ambient temperature. Solidification-induced segregation of interstitials is usually not a problem due to the ease with which they can diffuse...

A validation study in order to evaluate the efficiency of the inductively coupled plasma optical emission spectrometry (ICP-OES) in the analysis of minor elements (Manganese, Chromium, Copper, Iron and Titanium) in aluminium alloys was carried out. Aluminium casting samples were obtained from addition to aluminium baths of compressed powder compacts of each alloying element and aluminium (minit...

production of fe-c alloy powders by mechanical alloying was studied. fe and graphite elemental powdermixtures containing 0.8 and 1.5wt.% graphite were mechanically alloyed using a planetary ball mill. thestructural changes of powder particles during mechanical alloying were studied by x-ray diffractometery,scanning electron microscopy and microhardness measurements. for both compositions, mecha...

Nanostructured Pt-metal alloys have shown impressive catalytic properties for the oxygen reduction reaction (ORR) in acidic medium, but their long-term stability has not been satisfactory. Herein, we look beyond the traditional Pt-metal alloys and have developed a new kind of Pt-nonmetal alloy electrocatalyst for the ORR. Specifically, the novel catalyst is composed of interconnected platinum m...

Nanostructured Pt-metal alloys have shown impressive catalytic properties for the oxygen reduction reaction (ORR) in acidic medium, but their long-term stability has not been satisfactory. Herein, we look beyond the traditional Pt-metal alloys and have developed a new kind of Pt-nonmetal alloy electrocatalyst for the ORR. Specifically, the novel catalyst is composed of interconnected platinum m...

Thin films ofCo-W, 300-500 A thick, were electrodeposited at various compositions under a wide range ofplattng conditions. The saturation magnetization, coercivity, and squareness ratio of the films were derived from the parallel (in-plane) and perpendicular hysteresis loops, measured by using a vibrating sample magnetometer. The magnetic properties of the films are strongly related to their mi...

Earth abundant element clathrate phases are of interest for a number of applications ranging from photovoltaics to thermoelectrics. Silicon-containing type I clathrate is a framework structure with the stoichiometry A8-xSi46 (A = guest atom such as alkali metal) that can be tuned by alloying and doping with other elements. The type I clathrate framework can be described as being composed of two...

Grain boundary segregation provides a method for stabilization of nanocrystalline metals – the selection of an alloying element that will segregate to the boundaries can lower the grain boundary energy, attenuating the driving force for grain growth. The segregation strength, relative to mixing enthalpy, of a binary system determines the propensity for segregation stabilization. This relationsh...

This study investigates transport phenomena in the weld pool (WP) of gas tungsten arc (GTA) welding of Nickel to 304 stainless steel. A finite element 3D simulation of fluid flow and heat transfer of spot welding without consumable is accomplished which leads to prediction of the weld zone shape, weld penetration and dilution of alloying elements. The model includes magneto-hydrodynamics (MHD),...