Partial pyrolysis alters the chemical and textural properties of the lignocellulosic material. This work reports the effect of partial pyrolysis of olive wood on adsorption isotherms, kinetics and thermodynamics of chloro and nitrophenols. Shape of adsorption isotherms of the partially pyrolyzed sorbents was L3 for phenol; L2 for 2-nitrophenol and 2,4-dinitrophenol; H3 for 2-chlorophenol, 3-chl...

We present a new class of sequential adsorption models in which the adsorbing particles reach the surface following an inclined direction (shadow models). Capillary electrophoresis, adsorption in the presence of a shear, and adsorption on an inclined substrate are physical manifestations of these models. Numerical simulations are carried out to show how the new adsorption mechanisms are respons...

The measured dynamic surface tension of a water drop in air saturated by heptane vapor shows a sharp decrease from about 60 mN m−1 to 40 mN m−1, and less after a certain adsorption time. The observed adsorption kinetics is analyzed by a theoretical model based on multilayer adsorption of alkanes from the vapor phase at the water surface. The model assumes a dependence of the kinetic coefficient...

background & aims of the study: p-chloronitrobenzene is a benzoic compound that widely used in many chemical industrials. p-chloronitrobenzene may be absorbed through the skin and is suspected to causing cancer. so, developing an easy method to remove of it from the environment is necessary. equilibrium isotherms and adsorption kinetics of p-chloronitrobenzene onto modified silk waste were stud...

The kinetics of phosphate adsorbed on waste iron sludge was investigated in this study. Static batch adsorption experiments were performed at different initial phosphate concentrations, initial pH and temperature of solution. The initial adsorption rate increased with increasing the phosphate concentration. A shorter time, however, was required to reach adsorption equilibrium at low phosphate c...

The kinetics of K exchange were investigated in Ca-saturated samples from the Ap horizon of an Evesboro soil from Delaware. Biphasic kinetics characterized the first-order plots for K adsorption and desorption at 283 and 298K with the two simultaneous reactions being attributed to exchange sites with varying reactivity for K and Ca ions. The rapid reaction was ascribed to exchange sites of the ...

the sorption behavior of loofa-immobilized phanerochaete chrysosporium mycelia in two forms, live (l) and heat-inactivated (hia), was studied for the removal of hg2+ ions from aqueous solution. using the langmuir isotherm, the two key parameters for the sorption performance, qm and the coefficient b, were obtained; the qm values for hg2+ ions were 72.46 mg/g and 92.59 mg/g and the b coefficient...

The laboratory scale investigations on Cd removal characteristics of waste manganese leach residue (wMNR), generated by reduction roasting – ammonia leaching of manganese nodules have been studied. Adsorption studies show rapid kinetics of Cd adsorption. About 90% of total Cd adsorption occurs within 15 min contact time and equilibrium is attained within 30 min. The quantity of Cd adsorption in...

Cotton stalk (CS), cotton waste (CW), and cotton dust (CD), which are cotton wastes, were used as adsorbents to study the adsorption kinetics of methylene blue from aqueous solution. Kinetics of the batch adsorption experiment was investigated according to the pseudo-first order, the pseudo-second order, and the intraparticle diffusion models used commonly in the literature. The effects of the ...