We used first principles methods to study static and dynamical mechanical properties of the ferroelectric polymer poly(vinylidene fluoride) (PVDF) and its copolymer with trifluoro ethylene (TrFE). We use density functional theory [within the generalized gradient approximation (DFT-GGA)] to calculate structure and energetics for various crystalline phases for PVDF and P(VDF-TrFE). We find that t...

The outermost nanometres of a poly(vinylidene difluoride) (PVdF) based coil coating have been investigated using X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). A reference PVdF based coating formulation and three variations of this formulation were characterised by XPS. The addition of flow agent and/or acrylic co-polymers induced significa...

poly(vinylidene fluoride) (pvdf) fibers with two molecular weights were prepared via electrospinning process. in this process, the concentration of spinning depended drastically on the gelation process. also, it was experimentally smaller than obtained concentration in the solution entanglement number approach (sena). proof of this incompatibility was explained by the properties of pvdf and its...

Abstract. Flexible free standing polymer electrolyte films have been successfully prepared using a blend of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and poly(vinyl chloride) (PVC) doped with lithium perchlorate (LiClO4). The conductivity of the film was influenced by salt concentration and the degree of crystallinity. An optimum room temperature conductivity obtained was 2.10...

A superfine Li0.33La0.557TiO₃ (LLTO, 69.4 nm) was successfully synthesized by a facile solvent-thermal method to enhance the electrochemical properties of the lithium-ion battery separator. Co-axial nanofiber of cellulose and Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) was prepared by a co-axial electrospinning technique, in which the shell material was PVDF-HFP and the core was...