Nitrogenase enzymes mediate the six-electron reductive cleavage of cyanide to CH4 and NH3 . Herein we demonstrate for the first time the liberation of CH4 and NH3 from a well-defined iron cyanide coordination complex, [SiP(iPr) 3 ]Fe(CN) (where [SiP(iPr) 3 ] represents a tris(phosphine)silyl ligand), on exposure to proton and electron equivalents. [SiP(iPr) 3 ]Fe(CN) additionally serves as a us...

Changes in proliferative activity in epithelial cells of rat lenses maintained in organ culture for 24 hours have been characterized, and the effects of isoproterenol (IPR) and cyclic adenosine-3',5'-monophosphate(cAMP) derivatives added to the culture medium have been studied. Transient mitotic inhibition occurred within the first few hours of incubation with IPR as well as with monobutyryl an...

The well-defined copper(I) boryl complex [(IPr)Cu(Bpin)] [where IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, and pin = pinacolate: 2,3-dimethyl-2,3-butanediolate] deoxygenates CO2 rapidly and quantitatively, affording CO and the borate complex [(IPr)Cu(OBpin)]. The boryl may be regenerated by treatment with the diboron compound pinB-Bpin, giving the stable byproduct pinB-O-Bpin. The ...

We build a multi-sectoral North–South trade model to analyze international intellectual property rights (IPR) protection. By comparing the Nash equilibrium IPR protection standard of the South (the developing countries) with that of the North (the developed countries), we find that the former is naturally weaker than the latter. Moreover, we show that both regions can gain from an agreement tha...

I analyze the welfare implications of protecting intellectual property rights (IPRs) in developing countries through its impact on innovation, market structure, and technology transfer. FDI, tariffs, and cooperation are introduced to the strategic IPR literature. In a North-South framework, the Southern government sets the IPR policy strategically by anticipating the Northern firm’s decision on...

This paper studies the relationship between intellectual property rights (IPR) and the entry modes decision by multinational firms. A model is developed allowing firms to choose among export, foreign direct investment (FDI), and licensing. Firms in the recipient country may imitate the technology, and their abilities to do so depend both on the nature of each mode and on the level of IPR protec...

This paper aims at explicating the hegemonic pressure from the U.S. side and the constant resistance from the Chinese side during the U.S.-China IPR disputes in the cyberspace. The theory of hegemony and extended literature review reveal that during the U.S.-China IPR disputes in cyberspace, the dominant U.S. power has shaped the IPR world order so effectively for its own interests that China a...