Me et th ho od ds s U Us se ed d t to o A As ss se es ss s t th he e E Ef ff fe ec ct ti iv ve en ne es ss s o of f A Ad dv ve er rt ti is si in ng g o on n t th he e I In nt te er rn ne et t

Heterotetrametallic [{[Ti](μ-σ,π-C≡CSiMe3)2}Cu-bipy-C≡C-AuPh2PFc]PF6 (5) ([Ti] = (ηC5H4SiMe3)2Ti; Fc = (η-C5H4)(η-C5H5)Fe; bipy = 2,2`-bipyridine) is accessible by the consecutive reaction of FcPPh2-AuCl (1) with 5-ethynyl-2,2`-bipyridine (2) producing FcPPh2-AuC≡C-bipy (3) which further reacts with [{[Ti](μ-σ,π-C≡CSiMe3)2}Cu(N≡CMe)]PF6 (4) to give the title complex in which four different tran...

The title compound, [Fe(2)Ti(C(5)H(5))(4))(C(10)H(8)O(2)P(2)S(4))]·3C(4)H(8)O, contains a central seven-membered TiO(2)P(2)S(2) ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti-O distance being marginally longer for the anisyl derivative. Two tetra-hydro-furan solvent mol-ecules are each disordered on a twofold axis.

Solid-state direct diffusion bonding of commercially pure Titanium (Cp-Ti) and precipitation hardening stainless steel (PHSS) has been carried out in the temperature range of 800°C to 1000°C with an interval of 50°C for 3.6 ks under 3.5 Mpa uniaxial load in (4 to 6)×10 Pa vacuum. The effects of temperatures have been investigated with reference to bond strength. The examination revealed that th...

BACKGROUND This study aimed at measuring the quantities of Al, Ti and Fe in silica sand and allied materials employing a complexometric method in the same analyte and a stepwise indirect titration with EDTA. The method involves the complexation of Al, Ti and Fe with excess EDTA and the selective de-complexation of TiO-EDTA and Al-EDTA complexes with tartaric acid and NaF respectively. In additi...

Context. The chemical analysis of secondary stars of low mass X-ray binaries provides an opportunity to study the formation processes of compact objects, either black holes or neutron stars. Aims. Following the discovery of overabundances of α-elements in the Keck I/HIRES spectrum of the secondary star of Nova Scorpii 1994 (Israelian et al. 1999), we obtained VLT/UVES high-resolution spectrosco...

Sixteen samples of orange-red and yellow Fe-oxide earthy pigments mainly from bole grounds of Baroque paintings were studied by elemental and phase analysis and voltammetry. Fe, K, and Ti content were found to be suitable for further classification of those earthy pigments. According to the chemical and phase composition the yellow grounds were natural yellow ochres formed by intense chemical w...

AIM To develop an accurate finite element (FE) model for studying rotary endodontic instruments and to demonstrate the usefulness of the FE method in improving the knowledge of the mechanical behaviour of these instruments during root canal preparation. METHODOLOGY An accurate geometrical model of a Ni-Ti ProTaper F1 instrument was created. The interaction between the rotating instrument and ...

Excited states in the neutron-rich N = 38, 36 nuclei (60)Ti and (58)Ti were populated in nucleon-removal reactions from (61)V projectiles at 90 MeV/nucleon. The γ-ray transitions from such states in these Ti isotopes were detected with the advanced γ-ray tracking array GRETINA and were corrected event by event for large Doppler shifts (v/c ∼ 0.4) using the γ-ray interaction points deduced from ...