نتایج جستجو برای: β amino carbonyl compound
تعداد نتایج: 504939 فیلتر نتایج به سال:
The title compound, C(20)H(18)N(2)O, is composed of three aromatic rings, the dihedral angles between the phenyl and benzamide rings, and between the benzamide and aniline rings being 59.86 (9) and 46.57 (10)°, respectively. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen bond involving the amino H atom and the benzamide carbonyl O atom. In the crystal structure, C-H...
The title compound, C(15)H(15)NO(4)S, was prepared by simple condensation of methyl 2-amino-benzoate and 4-methyl-benzene-sulfonyl chloride. The dihedral angle between the benzene rings is 84.36 (6)°. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen-bonding inter-action involving the carbonyl group as acceptor, generating an S(6) graph-set motif.
Schiff bases are versatile ligands which are synthesized from the condensation of an amino compound with carbonyl compounds. These compounds and their metal complexes are very important as catalysts in various biological systems, polymers, dyes and medicinal and pharmaceutical fields. Their use in birth control, food packages and as an O2 detector is also outlined. This review summarizes the ap...
The title compound, C17H20N4O2, was prepared by the reaction between 1,3-di-amino-propane and isatoic anhydride in water. The carbonyl O atoms are involved in intra-molecular hydrogen bonding with the amine group and inter-molecular hydrogen bonding with an amide H atom of an adjacent mol-ecule. In the crystal, pairs of N-H⋯O hydrogen bonds link mol-ecules into inversion dimers and further N-H⋯...
The title compound, C(24)H(29)NO(7), is asymmetric with a chiral centre located in the pyran ring and crystallizes as a racemate. The coumarin ring system and the fused pyran ring make a dihedral angle of 10.46 (8)°. A short intra-molecular N-H⋯O hydrogen bond between the amino group and the vicinal carbonyl group generates an S(6) ring. Inter-molecular C-H⋯O inter-actions contribute to the sta...
The title compound, C(20)H(16)N(2)O(2), was synthesized by the reaction of 2-hydroxy-benzohydrazide with diphenyl-methanone. The dihedral angle between the phenyl rings is 76.28 (11)°. The amino H atom is involved in an intra-molecular N-H⋯O hydrogen bond. In the crystal structure, the hydr-oxy groups and carbonyl O atoms form inter-molecular O-H⋯O hydrogen bonds, which link the mol-ecules into...
In the title compound, C32H26Cl2F2N2O2, the tetra-hydro-pyridine ring adopts a distorted boat conformation. The chlorophenyl rings are inclined to one another by 55.2 (1)°, while for the fluorophenyl rings the dihedral angle is 80.7 (1)°. The amino group and carbonyl O atom are involved in an intra-molecular N-H⋯O hydrogen bond. In the crystal, weak C-H⋯O, C-H⋯F and C-H⋯Cl inter-actions link th...
In the title compound, C(13)H(17)NO, the dihedral angle between the aryl ring and the amino-acryl-aldehyde mean plane [N-C=C-C=O; maximum deviation = 0.0144 (9) Å] is 53.43 (4)°. There is an intra-molecular N-H⋯O hydrogen bond involving the amine and carbonyl groups. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming chains propagating along [001].
A camphor-derived sulfonimine with a conjugated carbonyl group, oxoimine 1 (O2SNC10H13O), reacts with amino acids (glycine, L-alanine, L-phenylalanine, L-leucine) to form a compound O2SNC10H13NC10H14NSO2 (2) which was characterized by spectroscopic means (MS and NMR) and supported by DFT calculations. The product, a single diastereoisomer, contains two oxoimine units connected by a -N= bridge, ...
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