Development of in-born porous nature of zirconium hydroxide nanopowders through a facile hydrogen (H2) gas-bubbles assisted borohydride synthesis route using sodium borohydride (NaBH4) and novel information on the temperature-mediated phase transformation, pore geometry as well as pore hysteresis transformation of in-born porous zirconium hydroxide nanopowders with the help of X-ray diffraction...

Metallic coatings on the inner surfaces of vacuum chambers are widely used in accelerators but impact coating resistivity beam coupling impedance and dynamics is often not sufficiently evaluated. In this paper, it shown that, for usual thickness, electrical can have a strong microwave instability threshold. particular, using different nonevaporable getters as examples, regime which with lower p...

The title compound, [Zr(CH(3))(C(15)H(39)N(4)Si(3))], is a unique example of a triamido-amine-supported zirconium-methyl complex that crystallized as a monomer with trigonal-bipyramidal geometry at zirconium, featuring a Zr-C bond of 2.2963 (16) Å.

A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.

A 16-year-old woman with congenitally missing permanent mandibular second premolars and central incisors presented for treatment. The prosthodontic treatment consisted of placing 2 internal tri-lobed narrow platform implants in the mandibular second premolar spaces, along with zirconium abutments and all-ceramic crowns. A 4-unit zirconium fixed partial denture was fabricated to restore the miss...

the structural and electrical properties of polyaniline-cobalt sulphate nanocomposite prepared by chemical method.polyaniline-cobalt sulphate nanocomposites were synthesized by the cobalt sulphate and ammonium persulphate and aniline.this paper reports on chemical technique using for synthesis of cobalt nanoparticles in the composite bridge is aniline. electrical conductivity of polyaniline wit...

ABSTRACT The phosphonate-substituted zirconium oxo clusters Zr6O2(OBu)12(O3PPh)4 and Zr7O2(OiPr)12(O3PCH2CH2CH2Br)6, with octahedrally coordinated Zr atoms, were synthesized by reaction of zirconium alkoxides with phosphonic acid bis(trimethylsilyl) esters. The basic structural motif are Zr3O(µ2-OR)3(OR)3 units which are connected in different ways. GRAPHICAL ABSTRACT

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr(6)O(4)(OH)(4)(OMc)(12) (OMc = CH(2)=CH(CH(3))COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.

in this study, isophthalic acid-zirconium(iv) nanocomposite has been prepared from zirconyl nitrate pentahydrate and potassium iodide, with isophthalic acid, (c8h6o4=benzene-1,3-dicarboxylic acid) as a ligand, via sonochemical method in ethylene glycol and methanol as solvents. the crystalline tetragonal zro2 has been produced by thermal decomposition of isophthalic acid-zirconium(iv) nanocompo...