Solid oxide electrochemical reactors (SOERs) may be operated in fuel cell (SOFC) or electrolyser (SOE) modes, at temperatures > 800 K, depending on electrolyte and electrode materials. In mode, current densities of ≥ ca. 104 A m−2 are achievable potential differences ideally the thermoneutral values 1.285 V for steam splitting 1.46 CO2 750 °C. As large scale chemical processes general, such req...

Gadolinium zirconate (GZ) is an attractive material for thermal barrier coatings (TBCs). However, a single layer GZ coating has poor cycling life compared to Yttria Stabilized Zirconia (YSZ). In this study, Solution Precursor High Velocity Oxy-Fuel (SP-HVOF) spray was used produce double GZ/YSZ TBC and the performance with YSZ TBC. The temperature behaviour of solution precursor studied, splat ...

Microstructural evolution of Nickel in Ni-YSZ fuel electrodes is one the main limiting degradation mechanisms solid oxide cells [1]. The redistribution ascribed to its high mobility and low wettability with YSZ, related interfacial surface tensions. Practically, manifests as agglomeration Ni, potentially accompanied by migration, mainly reported electrolysis mode.

The mechanisms for the resistance to sulfur poisoning at the triple phase boundary (TPB) of the Ni/yttria-stabilized zirconia (YSZ) system treated with Sn vapor are studied using the first-principles method based on density functional theory. Models with Sn dopant or adsorbate are proposed. It is found that the TPB model of the Ni/YSZ system with Sn dopant in Ni can to some extent restrain the ...

In this work, we found that sodium doping can be used to improve CO2 selectivity for supported Pt catalyst during methanol steam reforming. These materials are usually very active in the low temperature range; however, they are characterized by high selectivity of CO, which is a poison in downstream polymer electrolyte membrane fuel cells (PEM-FC) application. With Na doping, we found that CO2 ...

The bulk and emerging interface properties of magnetite Fe3O4/YSZ(001) heterostructures grown by pulsed laser deposition are investigated. Fe3O4 thin films (4–38 nm) grow epitaxially in (111) orientation undergo a Verwey transition at max. TV = 117±0.6K. Surprisingly, the formation interfacial Fe2O3 phase is observed albeit quasi-inert yttrium-stabilized zirconia (YSZ). Possible mechanisms incl...

The bulk and emerging interface properties of magnetite Fe3O4/YSZ(001) heterostructures grown by pulsed laser deposition are investigated. Fe3O4 thin films (4–38 nm) grow epitaxially in (111) orientation undergo a Verwey transition at max. TV = 117±0.6K. Surprisingly, the formation interfacial Fe2O3 phase is observed albeit quasi-inert yttrium-stabilized zirconia (YSZ). Possible mechanisms incl...

In situ FT-IR spectroscopy was exploited to study the adsorption of CO2 and CO on commercially available yttria-stabilized ZrO2 (8 mol % Y, YSZ-8), Y2O3, and ZrO2. All three oxides were pretreated at high temperatures (1173 K) in air, which leads to effective dehydroxylation of pure ZrO2. Both Y2O3 and YSZ-8 show a much higher reactivity toward CO and CO2 adsorption than ZrO2 because of more fa...

Percolation theory is generalized to predict the effective properties of specific solid oxide fuel cell composite electrodes, which consist of a pure ion conducting material (e.g., YSZ or GDC) and a mixed electron and ion conducting material (e.g., LSCF, LSCM or CeO2). The investigated properties include the probabilities of an LSCF particle belonging to the electron and ion conducting paths, p...

Thermal stability of composite cathodes for solid oxide fuel cells, the mixtures of (La0.8Sr0.2)0.95MnO(3-δ) (LSM) and (Y2O3)(x)(ZrO2)(1-x) (xYSZ, x = 3, 6, 8 and 10), is determined using in-situ neutron diffraction. Thanks to the most advanced high flux neutron source, our work highlights the visualization of the phase evolutions in heterogeneous material systems at high temperatures, along wi...