Metal-N4 (M-N4) macrocyclic complexes are interesting electrocatalysts due to their well-defined structures and rich molecular tuning. Among them, metal phthalocyanines have been widely studied for the carbon dioxide reduction reaction (CO2RR) in heterogeneous systems demonstrated good electrocatalytic performance. However, other like corroles porphyrins much less explored, often show inferior ...

The main interaction between pyridine and zeolites leads to form a hydrogen bond between the N atom of pyridine and OH groups of zeolites. The present work reports a theoretical study about the structural, vibrational and topological properties of the charge distribution of the molecular complexes between pyridine and a series of acids sites of zeolites. The calculated structural parameters...

a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...

the vo(iv) complexes of tridentate ono schiff base ligands derived from 2- aminobenzoicacid and salicylaldehyde derivatives were synthesized and characterized by ir, uv–vis and elemental analysis. electrochemical properties of the vanadyl complexes were investigated by cyclic voltammetry. a good linear correlation was observed between the oxidation potentials and the electron-withdrawing charac...

 A series of symmetric and asymmetric binuclear α-diimine nickel(II) complexes toward ethylene polymerization were successfully synthesized and characterized by 1HNMR. All the catalysts were typically activated with MAO and displayed good activity at room temperature under 1atm ethylene pressure. The symmetric catalyst containing isopropyl on l...

Ab initio calculations are carried out on the H2O•••N2, H2O•••H2, and H2O•••CO complexes. Infrared spectra of the complexes are investigated, with an emphasis on the effect of weak bonding on the frequencies and the infrared intensities of the monomers. Connections are explored between the computational results and the experimentally measured infrared spectra of ice surfaces covered by H2, N2, ...