OBJECTIVE In a clinical setting, lipoma can sometime show low signal intensity on susceptibility-weighted imaging (SWI) mimicking hemorrhage. The purpose of this study was to evaluate the fat-water interface chemical-shift artifacts between SWI and T2*-weighted imaging with a phantom study and evaluate SWI in lipoma cases. MATERIALS AND METHODS SWI, magnitude, high-pass filtered phase, and T2...

We used a time-resolved interfacial tension measurement method with quasi-elastic laser scattering to investigate the effects of electrolytes and various surfactants on the nonlinear dynamics of the chemical oscillation that occurred at a water/nitrobenzene interface when a surfactant was added to the interface through a capillary. For both cationic and anionic surfactants, an electrolyte in th...

We have studied the effect of weak solute-solvent attractions on the solvation of nonpolar molecules in water at ambient conditions using an extension and improved parameterization of the theory of solvation due to Lum, Chandler, and Weeks [J. Phys. Chem. B 1999, 103, 4570]. With a reasonable strength of alkanewater interactions, an accurate prediction of the alkane-water interfacial tension is...

The orientational dynamics of water at a neutral surfactant reverse micelle interface are measured with ultrafast infrared spectroscopy of the hydroxyl stretch, and the results are compared to orientational relaxation of water interacting with an ionic interface. The comparison provides insights into the influence of a neutral vs. ionic interface on hydrogen bond dynamics. Measurements are made...

We demonstrate the use of X-ray reflectivity to probe the electron density profile normal to the interface between two polar liquids. Measurements of the interfacial width at the neat nitrobenzene/water and the neat water/2-heptanone interfaces are presented. These widths are consistent with predictions from capillary wave theory that describe thermal interfacial fluctuations determined by the ...

Interfacial properties of native β-lactoglobulin monomers and their heat-induced fibers, of two different lengths, were investigated at pH 2, through surface tension measurements at water-air and water-oil interfaces and interfacial shear rheology at the water-oil interface. The applied heat treatment generates a mixed system of fibers with unconverted monomers and hydrolyzed peptides. The surf...

A finite element model for the reverberation and propagation in a shallow water waveguide with a sandy bottom was calculated for five different environments at a center frequency of 250 Hz. The various environments included a rough water/sediment interface, a rough air/water interface, roughness at both interfaces and downward and upward refracting sound speed profiles with roughness at both in...

The present study reports molecular dynamics simulations for biphasic systems comprising tributyl phosphate (TBP) in dodecane and uranyl nitrate in the aqueous phase, which are key chemical species in the well-known Pu-U extraction (PUREX) process. An attempt has been made to understand the nature of interface and mechanism of 'TBP associated uranyl' crossing under neutral and acidic conditions...

This paper reviews current knowledge of dynamic processes in New Zealand land-water ecotones drawing on published quantitative data wherever possible. Basic ecosystem processes in forested and natural unforested land-water ecotones are compared, and dynamic processes are discussed under the following headings: time scales of change; water movement; sediment trapping and transport; dissolved nut...

A new method to determine the pK, of chemical species at aqueous insulating interfaces is based on the discovery that the interface potential is linearly proportional to the measured second harmonic electric field. The proportionality constant is the effective third-order susceptibility and is the same for all aqueous interfaces studied, which has its origin in the polarization of bulk water in...