The need for high purity hydrogen for use in lowtemperature fuel cells has led to a resurgence of interest in the purification of hydrogen derived from reforming carbon -based feedstocks. A common process used to reduce the carbon monoxide concentration of the reformate gas to an acceptable level is the water gas shift reaction (WGSR). In the reaction, carbon monoxide is combined with water to ...

The water–gas shift (WGS) reaction (CO+H2OQCO2+H2) plays an important role in fuel processing for polymer electrolyte membrane (PEM) fuel-cell applications. The hydrogen in the reformate gas is upgraded by removal of the carbon monoxide, which is a strong poison of the anode catalysts in current PEM fuel cells. Active shift catalysts that are also stable under the operating conditions of practi...

Ni–CeO2–ZrO2 Catalysts for Water Gas Shift Reaction: Effect of CeO2

The energy system analysis of an integrated process producing synthetic natural gas (SNG) from woody biomass has been carried out. Two different configurations have proposed and modeled, considering the integration between gasification, solid oxide electrolysis (SOEC) catalytic reactors for methane synthesis. two investigated differ in size SOEC unit. In first configuration, unit is sized to in...

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The composite system of nanostructured gold and cerium oxide, with a gold loading 5–8 wt%, is reported in this work as a very good catalyst for low-temperature water–gas shift. Activity depends largely on the presence of nanosized ceria particles. Various techniques of preparation of an active catalyst are disscussed. The presence of gold is crucial for activity below 300 ◦C. A dramatic effect ...

Nanostructured Au–ceria is a promising new catalyst for low-temperature water-gas shift (LTS). Preparation, characterization, and catalytic properties of this material are reported in this paper. Gold–ceria was prepared by deposition–precipitation (DP), coprecipitation (CP), and gelation methods. The gold loading was varied between 1 and 8.3 at.%, while lanthanum used as a dopant in ceria, was ...

The kinetics of the high-temperature (1070-1134 K), low and high-pressure gasphase forward water-gas shift reaction were evaluated in an empty quartz reactor and a quartz reactor packed with quartz particles. The power law expression for the reaction rate was consistent with the Bradford mechanism and was invariant with respect to pressure. The experimental rate constant was lower than that pub...