Using phenylphosphonic acid, simple tungstate and copper(ii) compounds as starting materials, an organic-inorganic hybrid Strandberg-type organophosphotungstate, {[(Cu(H2O)(μ-bipy))2(C6H5PO3)2W5O15]}n (bipy = 4,4'-bipyridyl) (1), was assembled successfully under hydrothermal conditions and characterized by physico-chemical and spectroscopic methods. Compound 1 represents the first example of a ...

A highly luminescent freestanding film composed of the quantum cluster, Au(15), was prepared. We studied the utility of the material for specific metal ion detection. The sensitivity of the red emission of the cluster in the composite to Cu(2+) has been used to make a freestanding metal ion sensor, similar to pH paper. The luminescence of the film was stable when exposed to several other metal ...

zinc (zn) and copper (cu) are essential elements and increased plant growth in low concentrations. while high concentrations of these elements as a limiting factor, can cause adverse symptoms on the plants. in the present study, the uptake of micronutrient and macronutrient by pennyroyal were studied in a zn and cu deficiency and toxicity in soil. three levels of copper (0, 5 and 25 mg/kg) and ...

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A new amperometric biosensor for copper determination in food samples was developed through the immobilization of glucose oxidase (GOx) in polyacrylamide gel. The response time for the reaction was studied by observing the percentage inhibition with time at 0.0125 ppm concentration of Cu 2+ . 2.30 minutes was the optimized response time for the estimation of Cu 2+ ion in the solution. Linear ra...

A low-cost and high effective copper/aluminum (Cu/Al) bimetal has been developed for treatments of halogenated methanes, including dichloromethane, in near neutral and high pH aqueous systems. Bimetallic Cu/Al was prepared by a simple two-step synthetic method where Cu was deposited onto the Al surface. The presence of Cu on Al significantly enhanced rates of degradation of halogenated methanes...

Trace metals (Cd, Cr, Cu, Ni and Pb) concentrations in benthic sediments were analyzed through multi-step fractionation scheme to assess the levels and sources of contamination in estuarine, riverine and freshwater ecosystems in Niger Delta (Nigeria). The degree of contamination was assessed using the individual contamination factors (ICF) and global contamination factor (GCF). Multivariate sta...

In this work infiltration behavior of mechanical alloyed 75 wt% Cu – 25 wt% WC powders into porous WC compacts were studied. Owing to their ductile nature, initial Cu powders were directly added to mechanical alloying batch. On the other hand initial WC powders were high energy milled prior to mechanical alloying. Contact infiltration method was selected for densification and compacts prepared ...

Of the problematic agents in the ecosystem, heavy metals have special importance because they are unabsorbable and have physiologic effects on living beings at low concentrations. This study has investigated the effect of silk worm cocoon on reducing mobility of zinc (Zn) and copper (Cu) for the first time. To this end, 5% cocoon adsorbent was added to the studied soil, which had been contamina...