Although its value varies with the microstructure, hysteresis always accompanies hydride formation and decomposition in Pd(pure)-H, e.g., it is present even in nano-crystalline and thin films. Internal oxidation of Pd0.93Cr0.07 alloys leads to a pure Pd matrix containing nano-crystalline chromia precipitates. The characteristic hysteresis of Pd-H almost disappears in this form of Pd. The reason...

In this article, the sorption process of Cr, As and V as oxoanions using modified mordenite zeolite as sorbent has been experimentally estimated. The sample of mordenite zeolite was synthesized and modified and batch method was employed for analysis. Parameters such as sorbent dose, concentration of metal oxoanions in solution ranging from 50 to 5 μg/l and effect of contact time were studied. E...

The single-walled carbon nanotubes (SWNTs) synthesized by a catalytic decomposition of alcohol (Alcohol CVD method, ACCVD) are compared with HiPco SWNTs sample through optical spectroscopic measurements such as resonant Raman scattering, optical absorption and near infrared fluorescence. By ACCVD method, SWNTs were synthesized either on zeolite catalyst-support particles or directly on the surf...

The one-third paradigm of PBE0 density functional, PBE0-1/3, has shown to be a successful method for various properties. In this paper, the applicability of PBE0-1/3 is put into broader perspective for transition metals chemistry. As a comparative study, the performance of PBE0 and PBE0-1/3 has been assessed for geometries and vibrational frequencies of some transition metal hydrides and transi...

A possibility of the creation of potentiometric biosensor by adsorption of enzyme urease on zeolite was investigated. Several variants of zeolites (nano beta, calcinated nano beta, silicalite, and nano L) were chosen for experiments. The surface of pH-sensitive field-effect transistors was modified with particles of zeolites, and then the enzyme was adsorbed. As a control, we used the method of...

Many strongly correlated transition metal oxides exhibit a metal-insulator transition (MIT), the manipulation of which is essential for their application as active device elements. However, such manipulation is hindered by lack of microscopic understanding of mechanisms involved in these transitions. A prototypical example is VO2, where previous studies indicated that the MIT resistance change ...

A goal of our study was to find an alternative to nano-silver-based antimicrobial materials which would contain active silver immobilized in a solid matrix that prevents its migration into the surrounding environment. In this study, we investigated whether silver cations dispersed in an atomic form and trapped in an ion-exchanged zeolite show comparable antimicrobial activity to silver nanopart...

Thermal decomposition in a thermobalance of Fe(CO), adsorbed on alkali-metal, hydrogen-Y, dealuminated Y, L and omega zeolites proceeds stepwise via slow decarbonylation at low and high temperatures, separated by a fast endothermic reaction. Average CO/Fe ratios have been determined after each step. From i.r. results the former intermediates are assigned to species bearing bridging CO, whereas ...

considering the point that the existence of heavy metals in the wastewater are so dangerous forthe environment and it would have many bad consequences for all the creatures including human beings, wemust try out the ways that make us capable of adsorbing these heavy metals. in order to accomplish this goal we should use a method called adsorbing. in this study the adsorption of copper ions in h...

Optical phenomena supported by ordered and disordered chains of metal nano-particles on a metal surface are investigated by considering a particular example of gold nano-bumps on a gold surface. The TWs supported by these structures are analyzed by studying the frequency-wavenumber spectra of the fields excited by localized sources placed near the chain. Periodic nano-bump chains support travel...