Particles are important additives for altering and enhancing the properties of polymers. When the particle size approaching the fundamental length scale of the material, new mechanical, optical, and electrical properties arise, which are not present in the conventional macroscopic counterpart. For example, the dielectric constant of a polymer fluid can be increased by addition of ceramic nanopa...

The low-temperature heat capacities of nickel titanate (NiTiO3), cobalt titanate (CoTiO3), and cobalt carbonate (CoCO3) were measured between 2 and 300 K, and thermochemical functions were derived from the results. Our new data show previously unknown low-temperature lambda-shaped heat capacity anomalies peaking at 37 K for CoTiO3 and 26 K for NiTiO3. From our data we calculate standard molar e...

A model for the piezoelectric and pyroelectric activities of 0–3 composites of ferroelectric particles in a linear matrix has been developed based on the polarization behavior of the inclusions. The model is applied to simulate the piezoelectric activity of a lead zirconate titanate/epoxy system polarized under different fields and the piezoand the pyroelectric properties of lead titanate/ poly...

Methods to supply fresh water are becoming increasingly critical as the world population continues to grow. Small-diameter hazardous microbes such as viruses (20-100 nm diameter) can be filtered by size exclusion, but in this approach the filters are fouled. Thus, in our research, we are investigating an approach in which filters will be reusable. When exposed to ultraviolet (UV) illumination, ...

The bias-field-dependent dielectricity of ferroelectric thin films is studied by use of a multilayer model capable of modeling saturated and unsaturated hysteresis behavior under arbitrary fields. The simulated minor hysteresis loops at different bias fields are used to calculate the variation of dielectric permittivity with the bias field. The -E loops show asymmetric shifting along the field ...

Barium titanate/epoxy resin composites have been synthesized and tested for microwave absorption/ transmission. Nanocrystalline barium titanate (BaTiO3 or BT) was synthesized by the hydrothermal method and the composites of BT/epoxy resin were fabricated as thin solid slabs of four different weight ratios. BTwas obtained in the cubic phase with an average particle size of 21 nm, deduced from th...

We investigate the stability of aqueous barium titanate suspensions as a function of dispersant architecture, ionic strength, counterion valency, and particle size. Both pure polyelectrolytes, poly(acrylic acid) and poly(methacrylic acid) (PMAA), and comb polymer dispersants composed of a PMAA backbone with methoxy-poly(ethylene oxide) (mPEO) teeth of varying molecular weights are studied. Whil...

Abstract The polycrystalline strontium ferrate titanate (SrFe 0.1 Ti 0.9 O 3 , SFTO) thin films have been successfully prepared by chemical solution method. By analyzing the current-voltage ( I–V ) characteristics, we discuss conduction mechanism of SFTO. It is found that number oxygen vacancy defects increased Fe ion doping, making SFTO be with better resistive switching property. doping can a...

Titanate nanofibers containing silver have been demonstrated through the experiments reported herein to have effective antifungal and antiproliferative activities in the presence of UV light. The titanate nanofibers containing silver can be fabricated by means of ion exchange followed by a topochemical process in an environment suitable for reductive reactions. Excellent antibacterial, antifung...

Clean-up of wastewaters with coexisting heavy metals and organic contaminants is a huge issue worldwide. In this study, a novel anatase/titanate nanosheet composite material (labeled as TNS) synthesized through a one-step hydrothermal reaction was demonstrated to achieve the goal of simultaneous removal of Cr(VI) and 4-cholophenol (4-CP) from water. TEM and XRD analyses indicated the TNS was a ...