catena-Poly[[(l-me-thio-nine-κO)zinc]-μ3-(hydrogen phosphato)-κ(3) O:O':O''], [Zn{PO3(OH)}(C5H11NO2S)] n , a new one-dimensional homochiral zincophos-phate, was hydro-thermally synthesized using l-me-thio-nine as a structure-directing agent. The compound consists of a network of ZnO4 and (HO)PO3 tetra-hedra that form ladder-like chains of edge-fused Zn2P2O4 rings propagating parallel to [100]. ...

The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a hetero-atom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2''-terpyridine ligand and is coordinated by the N atoms of three thio-cyanate ions in an octa-hedral geometry whereas the Ag atom is coordinated by the four S atoms of four thio-cyanate ions in a distorted tetra-hedral geometry. Of the t...

The structure of the title compound, C(18)H(10)N(2)S(3), consists of a central thio-phene ring and two terminal thia-zole rings. The two S atoms of the thia-zole rings are trans to the thio-phene S atom sulfur. The thia-zole rings are approximately coplanar with the thio-phene ring, with dihedral angles of 6.23 (11) and 4.81 (11)° between them. In the crystal, zigzag chains are formed along [01...

IN THE TITLE COMPOUND [SYSTEMATIC NAME: 1-(3-phenyl-prop-2-eno-yl)thio-urea], C(10)H(10)N(2)OS, the acetyl-thio-urea fragment and the phenyl ring adopt an E configuration. The roughly planar but-2-enoyl-thio-urea fragment [maximum deviation = 0.053 (3) Å] forms a dihedral of 10.54 (11)° with the phenyl ring. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol-ecul...

The title compound, C(21)H(24)N(4)S(3), is a tripodal Schiff base that was obtained from the reaction of tris-(2-amino-eth-yl)amine (tren) and thio-phene-3-carbaldehyde. The compound forms a cavity with approximate C3 symmetry. One of the thio-phene units is disordered in a 0.764 (2):0.236 (2) ratio. In the crystal, the three thio-phene ligands are involved in intra-molecular C-H⋯π inter-action...

Both imine bonds of the title compound, C(21)H(21)N(3)O(4)S(2), were found to be in the E configuration. The terminal pyrrole and thio-phene rings are twisted by 2.5 (3) and 2.3 (2)°, respectively, from the mean plane of the central thio-phene to which they are attached. The structure is disordered by exchange of the terminal heterocyclic rings; the site occupancy factors are ca 0.8 and 0.2. Th...

In the title mol-ecule, C(22)H(19)NOS(2), the piperidine ring adopts an envelope conformation with the benzyl substituent in an equatorial position. Each of the olefinic double bonds has an E configuration. The dihedral angle between the two thio-phene rings is 1.55 (18)°. The thio-phene rings form angles of 72.21 (14) and 73.43 (14)° with the phenyl ring. Both thio-phene rings are disordered o...